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2,2,2-?????-1,1-????????????

2,2,2-?????-1,1-????????????
2,2,2-?????-1,1-???????????? ??? ???
?? ??:
66270-36-8
???:
2,2,2-?????-1,1-????????????
???(??):
2,2,2-?????-1,1-????????????
???:
2,2,2-TRICHLORO-1,1-DIMETHYLETHYL CHLOROFORMATE
???(??):
TCBOC-CHLORIDE;2,2,2-trichloro-1,1-dimethylethyl ester;β,β,β-trichloro-tert-butyl chloroformate;2,2,2-Trichloro-tert-butyl chloroformate;2,2,2-trichloro-1,1-dimethyl chloroformate;β,β,β-trichloro-tert-butoxycarbonyl chloride;2,2,2-trichloro-1,1-dimethyethyl chloroformate;2,2,2-TRICHLORO-1,1-DIMETHYLETHYL CHLOROFORMATE;BETA,BETA,BETA-TRICHLORO-TERT-BUTYL CHLOROFORMATE;2,2,2-Trichloro-1,1-diMethylethyl chloroforMate 96%
CBNumber:
CB6341886
???:
C5H6Cl4O2
??? ??:
239.91
MOL ??:
66270-36-8.mol

2,2,2-?????-1,1-???????????? ??

???
28-30 °C(lit.)
?? ?
83-84 °C14 mm Hg(lit.)
??
1.4953 (estimate)
?? ??
2-8°C
???
???: ??? 10%, ??, ??
??? ??
solid
BRN
1935464
InChI
InChI=1S/C5H6Cl4O2/c1-4(2,5(7,8)9)11-3(6)10/h1-2H3
InChIKey
GMELMFSDPDSXOZ-UHFFFAOYSA-N
SMILES
C(Cl)(OC(C)(C)C(Cl)(Cl)Cl)=O
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T
?? ???? ?? 23/24/25-34
????? 26-36/37/39-45
????(UN No.) UN 2928 6.1/PG 2
WGK ?? 3
F ?????? 4.5-10-19-21
?? ?? 6.1(a)
???? II
???? ??? 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard Classifications Acute Tox. 3 Oral
Skin Corr. 1B
????(GHS): Corrosion (GHS05)Skull and Crossbones (GHS06)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

2,2,2-?????-1,1-???????????? C??? ??, ??, ??

??

Used as easily removable acid- and base-stable protecting group for nitrogen, including amino acids and nucleosides; protecting group for alcohols.

?? ??

The solvolysis rate constants of 2,2,2-trichloro-1,1-dimethylethyl chloroformate in binary and pure solvents was studied.

2,2,2-?????-1,1-???????????? ?? ?? ? ???

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2,2,2-?????-1,1-???????????? ?? ??

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