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2,2′,5,5′-??????

2,2′,5,5′-??????
2,2′,5,5′-?????? ??? ???
?? ??:
15721-02-5
???:
2,2′,5,5′-??????
???(??):
2,2',5,5'-??????[1,1'-????]-4,4'-????;2,2′,5,5′-??????;2,2',5,5'-?????????
???:
2,2',5,5'-Tetrachlorobenzidine
???(??):
TCB;PK3;OIP3;PKM1 active human;2,2',5,5'-Tetrachlor;-Tetrachlorobenzidine;2,2’,5,5’-tetrachloro-benzidin;3,3’,6,6’-tetrachlorobenzidine;2,2',5,5'-tetrachlorobenzidine;2,2',5,5'-tetrachlorobenzidine
CBNumber:
CB6411730
???:
C12H8Cl4N2
??? ??:
322.02
MOL ??:
15721-02-5.mol
MSDS ??:
SDS

2,2′,5,5′-?????? ??

???
135-140 °C(lit.)
?? ?
477.67°C (rough estimate)
??
1.5309 (rough estimate)
???
1.6000 (estimate)
?? ??
-70°C
???
???? ???
??? ??
powder to crystal
?? ?? (pKa)
1.58±0.13(Predicted)
??
Light yellow to Yellow to Orange
???? ??
human
???
water: soluble
CAS ??????
15721-02-5(CAS DataBase Reference)
IARC
3 (Vol. 27, Sup 7) 1987
EPA
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T
?? ???? ?? 61
????? 53-45
WGK ?? 3
RTECS ?? DD1751000
TSCA TSCA listed
HS ?? 2921.59.8090
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.

2,2′,5,5′-?????? C??? ??, ??, ??

?? ??

2,2' ,5,5' -Tetrachlorobenzidine is made by the reduction of 2,5-dichloronitrobenzene with zinc dust and sodium hydroxide solution. The subsequent rearrangement is carried out using sulfuric acid or hydrochloric acid. The dihydrochloride melts at 230 ℃. Tetrachlorobenzidine is marketed as the free base and is used to produce yellow pigments.

Safety Profile

Suspected carcinogen with experimental carcinogenic and tumorigenic data. When heated to decomposition it emits very toxic fumes of NO, and Cl-.

2,2′,5,5′-?????? ?? ?? ? ???

???

?? ??


2,2′,5,5′-?????? ?? ??

???( 177)?? ??
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2,2′,5,5′-?????? ?? ??:

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