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???? ??? ???
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8017-16-1
???:
????
???(??):
????;????(POLYPHOSPHORICACID);?????????
???:
polyphosphoric acid
???(??):
PPA;PPA;PPA;polyphosphoric acids;Polyphoshoric acid;polyphosphoric aci;acidepolyphosphorique;Super Phos 105;Polyphosphoic Acid;condensedphosphoricacid
CBNumber:
CB6437945
???:
(H)n+2.(P)n.(O)3n+1
??? ??:
0
MOL ??:
Mol file

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???
-20°C
?? ?
550 °C
??
2.06 g/mL at 25 °C
???
2 hPa (20 °C)
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Store below +30°C.
???
???(? ???), ?(? ???)
??? ??
?? ??
?? ?? (pKa)
0.91[at 20 ℃]
Specific Gravity
2.06
??
???
??
Odorless
???
??? ? ??
??
Hygroscopic
Merck
14,7580
???
????. ?? ??? ???? ????. ???.
InChI
1S/O5P2.H3O4P/c1-2-7-4-3-6(1)5-7;1-5(2,3)4/h;(H3,1,2,3,4)
InChIKey
FVYIVXLIMHNYTD-UHFFFAOYSA-N
SMILES
[P](=O)(O)(O)O.[p]21[o][p]([o][o]2)[o][o]1
CAS ??????
8017-16-1(CAS DataBase Reference)
EPA
Polyphosphoric acids (8017-16-1)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C
?? ???? ?? 34
????? 45-36/37/39-25-26
????(UN No.) 3264
WGK ?? 1
TSCA TSCA listed
?? ?? 8
???? III
HS ?? 28092000
???? ??? 8A - Combustible corrosive hazardous materials
Hazard Classifications Eye Dam. 1
Met. Corr. 1
Skin Corr. 1B
?? ?? ??? 8017-16-1(Hazardous Substances Data)
???? ?? KE-29024
????(GHS): Corrosion (GHS05)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H290 ??? ???? ? ?? ?? ????? ?? 1 ?? P234, P390, P404
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P234 ??? ???? ?????.
P260 ??·?·??·???·??·...·????? ???? ???.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P301+P330+P331 ???? ?? ?????. ??? ?? ?? ???.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P310 ?? ????(??)? ??? ????. ???? ?? ????(??)? ??? ????.
P363 ?? ??? ??? ??? ?????.
P390 ????? ???? ?? ???? ??????.
P405 ???? ?????.
P406 ??? ???? ?????/...???? ??
P501 ...? ??? / ??? ?? ???.
NFPA 704
0
3 1

???? MSDS


Polyphosphoric acids

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Superphosphoric acid is made by the concentration of regular wet-process acid up to P2O5 concentrations of 78%. Granular polyphosphates suitable for bulk blending are made by reacting ammonia with regular wet process acid of 52% P2O5 content and using the heat of reaction to drive off water to produce a phosphate melt of 10-43-0, with about 40% of the phosphorus in the polyphosphate form. These materials are, however, not suitable for bulk blending due to their “sticky” nature (10).

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Viscous, water-white liquid. Water solu- ble. Does not crystallize on standing; hygroscopic. The commercial acid is a mixture of orthophos- phoric acid with pyrophosphoric, triphosphoric, and higher acids and is sold on the basis of its calcu- lated content of H3PO4, e.g., 115%. Superphospho- ric acid is a similar mixture sold at 105% H3PO4. These acids revert slowly to orthophosphoric acid on dilution with water.

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Polyphosphoric Acid is a ligand used as an analytical tool to image nanoparticles through photon emission topography. Used also in the synthesis of pharmaceuticals.

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ChEBI: A polymerized phosphorus oxoacid of general formula HO[PO2OH]nH formed by condensation of orthophosphoric acid molecules and containing a backbone chain consisting of alternating P and O atoms covalent y bonded together.

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Polyphosphoric acid (PPA) is widely employed as acylation and alkylation reagent in various reactions. It is a strong mineral acid with excellent dehydrating properties.

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Toxic by ingestion; strong irritant.

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Polyphosphoric acid is obtained by heating the wetprocess phosphoric acid. It contains around 72% phosphorus (as P2O5) and represents a series of phosphoric acids containing more than one atom of phosphorus (such as H4P2O7). The general formula is Hn+2PnO3n+1.

Solubility in water

Polyphosphoric acids are miscible with water, hydrolyzing to orthophosphoric acid with the generation of heat. They are insoluble in hydrocarbons and halogenated hydrocarbons. 

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