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?????
????? ??? ???
?? ??:
86-55-5
???:
?????
???(??):
1-????;?????;1-????
???:
1-Naphthoic acid
???(??):
1-NAPHTHALENECARBOXYLIC ACID;NAPHTHALENE-1-CARBOXYLIC ACID;NSC 37569;1-naphthoic;1-phthoic acid;1-Naphthoesure;1-NAPTHOIC ACID;1-Naphtoic Acid;α-Naphthoic acid;a-naphthoic acid
CBNumber:
CB6475509
???:
C11H8O2
??? ??:
172.18
MOL ??:
86-55-5.mol
MSDS ??:
SDS

????? ??

???
157-160 °C (lit.)
?? ?
300 °C (lit.)
??
1.398
???
1.4600 (estimate)
???
195°C
?? ??
Sealed in dry,Room Temperature
???
??? ?? ?? ?????. ??? ???, ???? ???? ???
?? ?? (pKa)
3.7(at 25℃)
??? ??
??
??
?? ???~??
Specific Gravity
1.398
pH ??
Non& uorescence (2.5) to blue & uorescence (3.5)
???
??? ???? ???? ? ????. ??? ?? ?? ?????.
?? ??(λmax)
293nm
Merck
14,6381
BRN
1908896
???
????. ???, ????? ???? ????.
?? ??
??????, ?? ??, ???, ???, ??, ??, ???? ??, ??, ???, ??? ???, ?? ?? ??, ???, ?????
InChI
1S/C11H8O2/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H,(H,12,13)
InChIKey
LNETULKMXZVUST-UHFFFAOYSA-N
SMILES
OC(=O)c1cccc2ccccc12
CAS ??????
86-55-5(CAS DataBase Reference)
NIST
1-Naphthalenecarboxylic acid(86-55-5)
EPA
1-Naphthalenecarboxylic acid (86-55-5)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36-24/25-37
WGK ?? 2
RTECS ?? QL0960000
TSCA TSCA listed
HS ?? 29163900
???? ??? 11 - Combustible Solids
???? ?? KE-25548
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H303 ??? ??? ? ?? ?? ?? ?? - ?? ?? 5 P312
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.
NFPA 704
1
2 0

????? MSDS


a-Naphthoic Acid

????? C??? ??, ??, ??

??? ??

Off-white to beige powder

??

1-Naphthoic acid is used as an intermediate for the synthesis of pharmaceuticals, photochemicals, plant growth hormones, dyes and other organic compounds.

?? ??

1-Naphthoic acid has been used as a novel asymmetric chromophore for exciton-coupled circular dichroism (ECCD), which can be used to induce chirality[1]. 1-Naphthoic acid has also been used as an organic synthesis reactant for the preparation of naphthanones, isocoumarin derivatives, and naphthalene carboxylic acid cellulose. Microcrystalline cellulose (MCC) and cellulose nanofibres (CNFs) were modified by esterification using 1-Naphthoic acid in a toluenesulfonyl chloride/pyridine solvent system to produce fluorophore labelled cellulose. Cellulose modification decreases the degradation temperature and hence the thermal stability of cellulose. After induction of naphthoate side chains, a glass transition temperature (Tg) of about 160 °C was observed. Cellulose naphthalenecarboxylate shows a strong ultraviolet (UV) absorption peak at 282 nm and has good fluorescent properties. Therefore, it can be used for fluorescent coatings, sensors and packaging[2].

Purification Methods

Crystallise the acid from toluene (3mL/g) (charcoal), pet ether (b 80-100o), or aqueous 50% EtOH. The amide has m 202o (from EtOH). [Beilstein 9 IV 2402.]

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