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1-CYCLOHEXEN-1-YL????????-

1-CYCLOHEXEN-1-YL????????-
1-CYCLOHEXEN-1-YL????????- ??? ???
?? ??:
28075-50-5
???:
1-CYCLOHEXEN-1-YL????????-
???(??):
1-CYCLOHEXEN-1-YL????????-
???:
1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-
???(??):
cyclohex-1-en-1-yl trifluoromethanesulfonate;cyclohexenyl triflate;1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-;cyclohexen-1-yl trifluoromethanesulfonate;1-Cyclohexenyl trifluoroMethanesulfonate 97%;Cyclohex-1-en-1-yl trifluoromethanesulphonate;CYCLOHEX-1-EN-1-YL TRIFLUOROMETHANESULPHONATE - NEW PRODUCT;Methanesulfonic acid, 1,1,1-trifluoro-, 1-cyclohexen-1-yl ester;Cyclohex-1-en-1-yl triflate, 1-{[(Trifluoromethyl)sulphonyl]oxy}cyclohex-1-ene
CBNumber:
CB6499417
???:
C7H9F3O3S
??? ??:
230.2
MOL ??:
28075-50-5.mol
MSDS ??:
SDS

1-CYCLOHEXEN-1-YL????????- ??

?? ?
84-87 °C/4 mmHg (lit.)
??
1.315 g/mL at 25 °C (lit.)
???
160 °F
?? ??
2-8°C
??? ??
??
??
??~??
InChI
1S/C7H9F3O3S/c8-7(9,10)14(11,12)13-6-4-2-1-3-5-6/h4H,1-3,5H2
InChIKey
WVSCRRLWRRANJY-UHFFFAOYSA-N
SMILES
FC(F)(F)S(=O)(=O)OC1=CCCCC1
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
????(UN No.) NA 1993 / PGIII
WGK ?? 3
HS ?? 2904990090
???? ??? 10 - Combustible liquids
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H227 ??? ?? ??? ?? ?? 4 ?? P210, P280, P370+P378, P403+P235,P501
??????:
P403+P235 ??? ? ?? ?? ???? ???? ?????.

1-CYCLOHEXEN-1-YL????????- C??? ??, ??, ??

??

Cyclohex-1-en-1-yl Trifluoromethanesulfonate is used a reactant in the regioselective preparation of phenylpyrrolidines via C-H functionalization of amines with aryl halides.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 277, 1986 DOI: 10.1021/jo00352a039

?? ??

1-Cyclohexenyl trifluoromethanesulfonate, also known as 1-cyclohexenyl triflate, is a cyclohexenyl sulfonate. Its trifluoromethylation reaction in the presence of different monodentate biaryl phosphine ligands has been investigated. The asymmetric Heck reaction of 1-cyclohexenyl trifluoromethanesulfonate using palladium complexes of phosphine oxazoline ligand has been studied.

1-CYCLOHEXEN-1-YL????????- ?? ?? ? ???

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1-CYCLOHEXEN-1-YL????????- ?? ??

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1-CYCLOHEXEN-1-YL????????- ?? ??:

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