??????????? ?(?????????? ?)
|
|
??????????? ?(?????????? ?) ??
- ?? ??
- Keep in dark place,Inert atmosphere,Room temperature
- ???
- sol (and forms 1:2 complexes with) benzene, toluene, xylene; sol nitromethane, liq SO2; insol HF, petroleum ether.
- ??? ??
- ??/???
- ??
- ???? ?? ???
- ???
- ?? ?????.
- ??
- Hygroscopic
- ?? ??
- ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
- ???
- ???
- ?? ??
- PEM ?? ??
?? ?? ???
- InChI
- InChI=1S/Ag.6FH.Sb/h;6*1H;/q+1;;;;;;;+5/p-6
- InChIKey
- GSXFODUDOAXUBF-UHFFFAOYSA-H
- SMILES
- [Sb+5]([F-])([F-])([F-])([F-])([F-])[F-].[Ag+]
- CAS ??????
- 26042-64-8(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xn,N,C | ||
|---|---|---|---|
| ?? ???? ?? | 20/22-51/53 | ||
| ????? | 61 | ||
| ????(UN No.) | UN 3260 8/PG 2 | ||
| WGK ?? | 2 | ||
| F ?????? | 3-8-10 | ||
| ?? ?? ?? | Corrosive/Hygroscopic | ||
| TSCA | TSCA listed | ||
| ?? ?? | 8 | ||
| ???? | III | ||
| HS ?? | 28432900 | ||
| ???? ??? | 8B - Non-combustible corrosive hazardous materials | ||
| Hazard Classifications | Acute Tox. 4 Inhalation Acute Tox. 4 Oral Aquatic Chronic 2 |
||
| ???? ?? | KE-05-1166 | ||
| ?????? ??? | 97-1-92 | ||
| ?? ? ???? | ????: ????; ???(??)????: ??? ?? ? ?? 25% ?? ??? ???. ??, ?? ?(Silver chloride) ? ?? ?(Silver fulminate)? ?? |
??????????? ?(?????????? ?) C??? ??, ??, ??
??? ??
white to pale yellow crystalline powder??
Silver Hexafluoroantimonate(V) is used as a catalyst in the synthesis of isocoumarins through benzothiadiazine-fused.?? ??
Silver hexafluoroantimonate has been made from SbF3 (or Sb2O3), AgCl, and Bromine Trifluoride, but is more readily prepared by reacting Antimony(V) Fluoride and Silver(I) Fluoride in anhydrous HF at -78 to 0 °C, washing with pet ether, and drying in vacuo.?? ??
Silver hexafluoroantimonate is useful as a metathesis reagent with organic and organometallic halides; a mild Lewis acid catalyst for the rearrangement of α-haloketones, pinacols, epoxides, and propargyl esters.??????????? ?(?????????? ?) ?? ?? ? ???
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?? ??
??????????? ?(?????????? ?) ?? ??
???( 164)?? ??
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??????????? ?(?????????? ?) ?? ??:
??? ??????? ?????????? ? ??????? ??? ???? ??????????? ?(?????????? ?)
Hydrogen fluoride
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
Trisodium hexafluoroaluminate
Lithium hexafluorophosphate
Potassium hexafluorophosphate
Ammonium hexafluorophosphate
Sodium hexafluoroantimonate
tert-Butyllithium
HEXAFLUOROANTIMONIC ACID
SILVER HEXAFLUOROSILICATE
SILVER HEXAFLUOROSILICATE, AG2SIF6