???(III) ?????
|
|
???(III) ????? ??
- ???
- 763°C (dec.)
- ??
- 5.3 g/mL at 25 °C(lit.)
- ?? ??
- Inert atmosphere,Room Temperature
- ???
- 623.82g/l ???
- ??? ??
- ????
- ??
- ???
- ??????(pH)
- <2 (H2O, 20℃)Aqueous solution
- ???
- ?? ???? ?????.
- Merck
- 14,5088
- ???
- ???
- InChI
- InChI=1S/3ClH.Ir.H2O/h3*1H;;1H2/q;;;+3;/p-3
- InChIKey
- MJRFDVWKTFJAPF-UHFFFAOYSA-K
- SMILES
- [Ir](Cl)(Cl)Cl.O
- CAS ??????
- 14996-61-3(CAS DataBase Reference)
???(III) ????? C??? ??, ??, ??
??
???(III) ?????? ??? ??? ???, ???????????? ???(III) ??? ???? ? ???? ?? ????. ? ??? ?? ????? ???? ????????(OLED), ?? ?? ???, ?? ? ????? ??? ?? ???? ??[1].
??? ??
Black solid??
Iridium(III) chloride hydrate can be usually used for the preparation of other iridium compounds such as Vaska′s complex, trans-[IrCl(CO)(PPh3)2].?? ??
[1] Kubota, K., Endo, T., Ito, H. (2024). Solid-state mechanochemistry for the rapid and efficient synthesis of tris-cyclometalated iridium(iii) complexes?. Chemical Science, 9, 3365–3371. https://doi.org/10.1039/D3SC05796H
???(III) ????? ?? ?? ? ???
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?? ??
???(III) ????? ?? ??
???( 343)?? ??
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