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762-04-9
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???(??):
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Diethyl phosphite
???(??):
DIETHYL PHOSPHONATE;PHOSPHONIC ACID DIETHYL ESTER;1-ethoxyphosphonoyloxyethane;DIETHYL HYDROGEN PHOSPHITE;Diethoxyphosphine oxide;diethylacidphosphite;Diethyl phosphite,98%;Phosphorous acid diethyl;C4H11O3P;OPH(OC2H5)2
CBNumber:
CB7318904
???:
C4H11O3P
??? ??:
138.1
MOL ??:
762-04-9.mol
MSDS ??:
SDS

???????? ??

???
-70 °C
?? ?
50-51 °C/2 mmHg (lit.)
??
1.072 g/mL at 25 °C (lit.)
???
7hPa at 20℃
???
n20/D 1.407(lit.)
???
180 °F
??? ??
??
??
???
Specific Gravity
1.072
???
???(????)
??
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN
605759
Henry's Law Constant
1.7×100 mol/(m3Pa) at 25℃, HSDB (2015)
???
????. ????, ??, ????, ???? ???? ????. ??? ???? ??? ? ????. ?? ??.
InChI
1S/C4H11O3P/c1-3-6-8(5)7-4-2/h8H,3-4H2,1-2H3
InChIKey
MJUJXFBTEFXVKU-UHFFFAOYSA-N
SMILES
[H]P(=O)(OCC)OCC
LogP
-0.15
CAS ??????
762-04-9(CAS DataBase Reference)
NIST
Phosphonic acid, diethyl ester(762-04-9)
EPA
Diethyl phosphite (762-04-9)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38-43
????? 26-36/37/39-37/39-28-27
WGK ?? 1
RTECS ?? TG7875000
F ?????? 10-13-21
TSCA TSCA listed
HS ?? 29209014
???? ??? 10 - Combustible liquids
Hazard Classifications Eye Dam. 1
Skin Sens. 1B
?? ?? ??? 762-04-9(Hazardous Substances Data)
????(GHS): Corrosion (GHS05)Exclamation Mark (GHS07)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 1 ?? P280, P305+P351+P338, P310
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P272 ??? ??? ??? ??? ???? ???.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P333+P313 ????? ?? ??? ???? ???? ??·??? ????.
NFPA 704
2
2 0

???????? MSDS


Diethyl hydrogen phosphonate

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? ??? ?? ??? DEG C? 22? ?? 24 ?? ?? ?? ?? ??? ??? ?? ?? ?? ??? 360 ℃, ??? ?? ????, ??? ??? ????? ?? ??, ??? ?? ??? ?? , ???, ??, ??? ? ?? ?? ??? (1.184 ℃??) ?? 20, ?? ??? (1.5900 ℃??) ??? 20, ????.?? 3 ?? ????? ??.?? ?? ?? ??? (TPPI)

??

?? ?? ???? ?? ??? ?? ???? ??? ????, ?? ?? ??? ?? ??? ??? ????. ??? ?? ?????, ?? ????, ABS ??, ??? ??, ?? ?? ? ?? ??? ????, ???? ???? ?? ??? ??? ?? ? ????, ??? ?? ?? ??, ?? ? ??? ?? ??, ??? ?? ????? ????, ?? ??? ?? - ???, ???? ??? ??, ?? ??? ???? ??? ???? ?? ??,?? ??? ? ???? ?? ???, ?? ?? ??? ??? ?? ????? ??.

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colourless liquid

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Diethyl phosphite (DEPI) is a versatile reactive intermediate used in the production of various phosphorus based substances. It may be used to prepare the nickel chloride-diethyl phosphite system, efficient catalyst for the cross-coupling reaction between various functionalized arylzinc halides and aryl bromides, triflates and activated chlorides.
It may be used:
  1. in the stereoselective synthesis of β-fluorinated alkylphosphonates
  2. Used in synthesis of homoallylic bromide
  3. Used in synthesis of series of carbazole-based α-aminophosphonates
  4. used as an extraction agent and phosphate intermediate.
  5. Used in synthesis of pesticides kitazine and phosethyl-Al as well as synthetic O, O-diethyl phosphoryl chloride.
  6. used for the synthesis of plasticizers, flame retardants, etc.
  7. Diethyl phosphite is reported to be chemical warfare agent (CWA) simulant, simulant for nerve agents sarin, soman, tabun, and VX.

??

ChEBI: A phosphonic ester that is the diethyl ester of phosphonic acid.

?? ??

Diethyl phosphite is reported to be chemical warfare agent (CWA) simulant, simulant for nerve agents sarin, soman, tabun, and VX.

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