(R)-(+)-TolBINAP
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(R)-(+)-TolBINAP ??
- ???
- 255-257 °C
- ??
- +156° (c 0.5, C6H6)
- ?? ?
- 754.4±60.0 °C(Predicted)
- ?? ??
- Inert atmosphere,Room Temperature
- ??? ??
- ??
- ??
- ???? ?????
- ??? (Optical Rotation)
- [α]20/D +162°, c = 0.5 in benzene
- ???
- ?? ???.
- ?? ??(λmax)
- 223nm(EtOH)(lit.)
- InChIKey
- IOPQYDKQISFMJI-UHFFFAOYSA-N
- SMILES
- P(C1C=CC(C)=CC=1)(C1C=CC(C)=CC=1)C1C=CC2=CC=CC=C2C=1C1C2=CC=CC=C2C=CC=1P(C1C=CC(C)=CC=1)C1C=CC(C)=CC=1
- CAS ??????
- 99646-28-3(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xi | ||
|---|---|---|---|
| ?? ???? ?? | 36/37/38 | ||
| ????? | 37/39-26 | ||
| WGK ?? | 3 | ||
| TSCA | No | ||
| HS ?? | 29310099 | ||
| ???? ??? | 11 - Combustible Solids |
(R)-(+)-TolBINAP C??? ??, ??, ??
??? ??
White to cream powder??
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is used as chiral catalyst ligand. (R)-T-BINAP complexes derived from rhodium precursors are used for the asymmetric hydroformylation of vinyl acetate. It is a catalysts used for reductive amination of ketones, Pt dications for cation trapping, Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives.?? ??
BINAP is based on a bis naphthalene backbone with different phosphine derivatives. 2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl (p-Tol-BINAP)·AgF complex catalyzed asymmetric Mukaiyama-type aldol reaction is reported.(R)-(+)-TolBINAP ?? ?? ? ???
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N,N-?????????
(R)-1,1'-?-2-???
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4-??????
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1,2-??????
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(R)-(+)-TolBINAP ?? ??
???( 156)?? ??
| ??? | ?? | ??? | ?? | ?? ? | ?? |
|---|---|---|---|---|---|
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(R)-(+)-TolBINAP ?? ??:
???? [(S) - (+) - 2,2'- ?? (? ?? ?? ??) -1,1'- ?? ?? ?] ??? (II) ???? [(R) - (+) - 2,2'- ?? (? ?? ?? ??) -1,1'- ?? ?? ?] ??? (II)
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
Bis(diphenylphosphino)methane
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE
(R)-DM-BINAP
(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
1,1'-BINAPHTHYL
rac-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl ,2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)
Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)