ChemicalBook >?? ???? >?? ??>?? ?>????, ???? ? ?? ???>??? ????? ???(III)

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?? ??:: 13963-58-1

???:: ??? ????? ???(III)

???(??):: ????????;???????????(III);????????;?????????? ??(III);?????(3-), ??????-, ??????;?????(3-), ????(????-kC)-, ??????, (OC-6-11)-;?????(3-), ????(????-kC)-, ??? (1:3), (OC-6-11)-;??? ??? ?????? (CoK3(CN)6);?????? ???????????;??????????????;??? ?????????(III) (K3[Co(CN)6]);??? ?????????;??? ??? ??????;?????????? ???

???:: Potassium hexacyanocobaltate(III)

???(??):: POTASSIUM HEXACYANOCOBALTATE;POTASSIUM COBALTICYANIDE;Tripotassium hexacyanocobaltate;tate(III);Hexacyanocobalt;potassiumcobalticyanine;COBALT POTASSIUM CYANIDE;Potassium hexacyanocobaL;POTASSIUM HEXACYAN COBALATE;Potassium cobaltihexacyanide

CBNumber:: CB7334568

???:: C6CoKN6(-2)

??? ??:: 254.14

MOL ??:: 13963-58-1.mol

MSDS

?? ?? 198

??? ????? ???(III) ??

???: decomposes, forming olive green mass [MER06]

??: 1.878 g/mL at 25 °C (lit.)

?? ??: Keep in dark place,Inert atmosphere,Room temperature

???: very soluble in H2O; insoluble in ethanol

??? ??: ??? ??

??: ?? ????? ?? ??

Specific Gravity: 1.906

???: ??

??: Light Sensitive

Merck: 14,7637

?? ??: ACGIH: TWA 0.02 mg/m3
NIOSH: IDLH 25 mg/m3

???: ????. ?? ???? ???? ????.

InChI: InChI=1S/6CN.Co.K/c6*1-2;;/q6*-1;+3;+1

InChIKey: DCWJDZBCZORDFX-UHFFFAOYSA-N

SMILES: [Co+3]([C-]#N)([C-]#N)([C-]#N)([C-]#N)([C-]#N)[C-]#N.[K+]

CAS ??????: 13963-58-1(CAS DataBase Reference)

EPA: Cobaltate(3-), hexakis(cyano-.kappa.C)-, tripotassium, (OC-6-11)- (13963-58-1)

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	T,Xn
?? ???? ??	23/24/25-33-32-22
?????	28-36/37-45-7/9-24/25
????(UN No.)	UN 1588 6.1/PG 2
WGK ??	3
RTECS ??	GF9470000
TSCA	TSCA listed
?? ??	6.1(b)
????	III
HS ??	28419000
???? ???	13 - Non Combustible Solids
??	mouse,LD50,oral,1529mg/kg (1529mg/kg),Journal of Pharmaceutical Sciences. Vol. 52, Pg. 59, 1963.
???? ??	KE-34763
?????? ???	97-1-90
?? ? ????	????: ????; ???(??)????: ???? ??? ? ?? 1% ?? ??? ???. ??, ????(Ferric ferrocyanide), ?????(Ferrocyanide, salts), ?????(Ferricyanide, salts) ? ? ? ??? ??? ???? ??

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H302	??? ???	?? ?? ?? - ??	?? 4	??	P264, P270, P301+P312, P330, P501
H317	????? ?? ??? ??? ? ??	?? ??? ??	?? 1	??	P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H351	?? ??? ??? ??? (????? ?? ???? ???? ???? ??? ?? ????? ??? ???? ??)	??? ??	?? 2	??	P201, P202, P281, P308+P313, P405,P501

??????:

P201	?? ? ?? ???? ?????.
P261	??·?·??·???·??·...·????? ??? ????.
P280	????/???/???/?????? ?????.
P405	???? ?????.

NFPA 704

	0
3		0

??? ????? ???(III) MSDS

Potassium hexacyanocobaltate(III)

??? ????? ???(III) C??? ??, ??, ??

??? ??

moist light yellow crystals

??

It is applied in formation of a xerogel via a cyanogel, the gel has potential use in solid-state gas sensors. It is also used as reagent.

Purification Methods

Crystallise it from water to remove traces of HCN. Its solubility in 87-88% EtOH is 1 in 7500 at 20o. [Glemser in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1542 1965.]

??? ????? ???(III) ?? ?? ? ???

???

?? ??

??? ????? ???(III) ?? ??

???( 198)?? ??

???	??	???	??	?? ?	??
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??? ????? ???(III) ?? ??:

???? ???? ?? ??? ????? ???(III) Potassium cyanate COBALT(II) CYANIDE

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