ChemicalBook >?? ???? >?? ??>?? ??>? ??>(-)-B-?????????????

(-)-B-?????????????

(-)-B-????????????? ??? ???

?? ??:: 99438-28-5

???:: (-)-B-?????????????

???(??):: (-)-B-?????????????

???:: (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE

???(??):: CID 5114394;(+)-B-methoxydiisocamphenylborane;(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE;(+)-B-Methoxydiisopinocampheylborane;(-)-DIISOPINOCAMPHEYLMETHOXYBORANE HYDRATE;(+)-B-Methoxydiisopinocampheylborane;(+)-B-methoxydiisopinocampheylborane hydrate;(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE HYDRATE;(-)-beta-Methoxydiisopinocampheylboranehydrate;cis-1,2,3,4-Tetrahydro-2-phenyl-1-naphthaleneaceticaci

CBNumber:: CB7343524

???:: C21H37BO

??? ??:: 316.33

MOL ??:: 99438-28-5.mol

MSDS ??:: SDS

?? ?? 48

(-)-B-????????????? ??

?? ?: 365.6±9.0 °C(Predicted)

??: 0.95±0.1 g/cm3(Predicted)

???: >230 °F

?? ??: 2-8°C

??? ??: solid

??: Colorless to light yellow Solid

BRN: 6370228

InChI: InChI=1S/C21H37BO/c1-12-15-8-13(19(15,2)3)9-16(12)21(6)17-10-14(20(17,4)5)11-18(21)22-23-7/h12-18,22H,8-11H2,1-7H3/t12-,13+,14-,15+,16+,17+,18+,21-/m1/s1

InChIKey: BRIUCEGTDHQYCH-VSDAKGBHSA-N

SMILES: B([C@H]1C[C@@]2([H])C[C@@]([H])(C2(C)C)[C@]1([C@H]1C[C@]2([H])C[C@]([H])(C2(C)C)[C@H]1C)C)OC

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	Xi
?? ???? ??	36/37/38
?????	26-36
WGK ??	3
F ??????	10-21
???? ???	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H315	??? ??? ???	????? ?? ?????	?? 2	??	P264, P280, P302+P352, P321,P332+P313, P362
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??	P264, P280, P305+P351+P338,P337+P313P
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??

??????:

P261	??·?·??·???·??·...·????? ??? ????.
P264	?? ??? ?? ??? ????.
P264	?? ??? ?? ??? ????.
P271	?? ?? ??? ? ?? ???? ?????.
P280	????/???/???/?????? ?????.
P302+P352	??? ??? ??? ?? ????.
P305+P351+P338	?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

(-)-B-????????????? C??? ??, ??, ??

??

(+)-B-Methoxydiisopinocampheylborane is a chiral catalyst used in synthetic organic chemistry such as the bacterial macrolide glycoside (-)-Lyngbyaloside B which maintains antiproliferative activity.

(-)-B-????????????? ?? ?? ? ???

???

?? ??

(+)-Ipc2B(??),????1M

(-)-B-????????????? ?? ??

???( 48)?? ??

???	??	???	??	?? ?	??
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(-)-B-????????????? ?? ??:

?? (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Methoxydiethylborane (1R)-(+)-TRANS-PINANE (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE Disiamylborane

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