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1-Boc-????

1-Boc-????
1-Boc-???? ??? ???
?? ??:
86953-79-9
???:
1-Boc-????
???(??):
1-Boc-????
???:
1-Boc-Pyrrolidine
???(??):
N-Boc;n-boc-pyrrolidine;Tert-Butylpyrrolidine-1-Carboxylate;NT 0186;1-BOC-PYRROLIDINE;N-1-BOC-Pyrrolidone;N-T-BOC-PYRROLIDINE;N-T-Boc-Pyrrolidone;N-Boc-pyrrolidine 97%;1-Boc-pyrrolidine,96%
CBNumber:
CB7361768
???:
C9H17NO2
??? ??:
171.24
MOL ??:
86953-79-9.mol
MSDS ??:
SDS

1-Boc-???? ??

?? ?
80 °C/0.2 mmHg (lit.)
??
0.977 g/mL at 25 °C (lit.)
???
n20/D 1.449(lit.)
???
187 °F
?? ??
Keep in dark place,Sealed in dry,Room Temperature
???
?????, ???? ???
??? ??
??
?? ?? (pKa)
-1.28±0.20(Predicted)
??
???
BRN
4664750
InChI
InChI=1S/C9H17NO2/c1-9(2,3)12-8(11)10-6-4-5-7-10/h4-7H2,1-3H3
InChIKey
LPQZERIRKRYGGM-UHFFFAOYSA-N
SMILES
N1(C(OC(C)(C)C)=O)CCCC1
CAS ??????
86953-79-9(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36
????(UN No.) NA 1993 / PGIII
WGK ?? 3
?? ?? ?? Irritant
HS ?? 29339900
???? ??? 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
???? ?? 2009-3-4127
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
2
2 0

1-Boc-???? C??? ??, ??, ??

??? ??

liquid

??

1-Boc-pyrrolidine is a boc-protected cyclic amine used as a building block in the preparation of diastereomers by usually undergoing α'-lithiations and electrophilic substitution reactions.

?? ??

N-Boc-pyrrolidine is an N-substituted pyrrolidine. It is reported that the reactivity of N-Boc-pyrrolidine towards C-H insertion reaction is 2000 times more than cyclohexane. It undergoes α-arylation in the presence of a palladium catalyst with high enantioselectivity.

1-Boc-???? ?? ?? ? ???

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1-Boc-???? ?? ??

???( 233)?? ??
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1-Boc-???? ?? ??:

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