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5-Amino-1-naphthalenesulfonic acid

5-Amino-1-naphthalenesulfonic acid ??? ???
?? ??:
84-89-9
???:
5-Amino-1-naphthalenesulfonic acid
???(??):
5-AMINONAPHTHALENE-1-SULFONIC ACID;laurentacid;Laurens Acid;LAURENTS ACID;LAURENT'S ACID;1,5-AMINO ACID;LABOTEST-BB LT01138428;5-SULFO-1-NAPHTHYLAMINE;1-AMINO-5-SULFONAPHTHALENE;Laurent Acid(1.5 cleves acid)
CBNumber:
CB7713334
???:
C10H9NO3S
??? ??:
223.25
MOL ??:
84-89-9.mol
MSDS ??:
SDS

5-Amino-1-naphthalenesulfonic acid ??

???
>300°C
?? ?
220°C (rough estimate)
??
1.3588 (rough estimate)
???
1.6500 (estimate)
???
??? ?? (?? ???), DMSO (?? ???)
?? ?? (pKa)
pK1: 3.69 (25°C)
??? ??
powder to crystal
??
Purple to Dark purple to Dark red
???
??? ?? ?????.
Merck
14,6404
BRN
2214149
InChI
1S/C10H9NO3S/c11-9-5-1-4-8-7(9)3-2-6-10(8)15(12,13)14/h1-6H,11H2,(H,12,13,14)
InChIKey
DQNAQOYOSRJXFZ-UHFFFAOYSA-N
SMILES
Nc1cccc2c(cccc12)S(O)(=O)=O
CAS ??????
84-89-9(CAS DataBase Reference)
EPA
1-Naphthalenesulfonic acid, 5-amino- (84-89-9)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C
?? ???? ?? 20/21/22-34
????? 26-36/37/39-45
????(UN No.) UN 2585 8/PG 3
WGK ?? 3
RTECS ?? QK1270500
TSCA TSCA listed
HS ?? 2921.45.2000
?? ?? 8
???? III
???? ??? 8B - Non-combustible corrosive hazardous materials
Hazard Classifications Acute Tox. 4 Dermal
Skin Corr. 1B
???? ?? KE-01498
????(GHS): Corrosion (GHS05)Exclamation Mark (GHS07)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H312 ??? ???? ??? ?? ?? ?? - ?? ?? 4 ?? P280,P302+P352, P312, P322, P363,P501
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H332 ???? ??? ?? ?? ?? ?? ?? 4 ?? P261, P271, P304+P340, P312
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P310 ?? ????(??)? ??? ????. ???? ?? ????(??)? ??? ????.
NFPA 704
0
1 0

5-Amino-1-naphthalenesulfonic acid C??? ??, ??, ??

??? ??

1-Aminonaphthalene-5-sulfonic acid [84- 89-9]. (5-aminonaphthalene-1-sulfonic acid), Laurent’s acid, L acid, Purpurin acid, C10H9NO3S, Mr 223.24, crystallizes from hot water as needles of the monohydrate. The alkalimetal salts are all readily soluble in water. Bromination yields the 2,4-dibromo derivative, vigorous nitration gives 2,4-dinitro-1- hydroxynaphthalene, and sulfonation results in 1-aminonaphthalene-2,5,7-trisulfonic acid. 1- Hydroxynaphthalene-5-sulfonic acid is obtained by heating 104 with aqueous bisulfite (reverseBucherer reaction) or via the diazo compound. Caustic fusion produces 5-amino-1-hydroxynaphthalene. Coupling with diazo compounds takes place in the 2-position.

??

Intermediate of dyestuff

Purification Methods

Crystallise the acid under nitrogen from boiling water and dry it in a steam oven [Bryson Trans Faraday Soc 47 522, 527 1951]. [Beilstein 14 IV 2800.]

5-Amino-1-naphthalenesulfonic acid ?? ?? ? ???

???

?? ??


5-Amino-1-naphthalenesulfonic acid ?? ??

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5-Amino-1-naphthalenesulfonic acid ?? ??:

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