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Diethyl bromodifluoromethanephosphonate

Diethyl bromodifluoromethanephosphonate ??? ???
?? ??:
65094-22-6
???:
Diethyl bromodifluoromethanephosphonate
???(??):
DIETHYL (BROMODIFLUOROMETHYL)PHOSPHONATE;BROMODIFLUOROMETHYL DIETHYLPHOSPHONATE;Diethyl P-(bromodifluoromethyl)phosphonate;Diethyl bromodifluoromethanephosphonat;BROMODIFLUOROMETHANE DIETHYL PHOSPHATE;Diethyl bromodifluoromethanephosphonate;Bromodifluoromethyldiethylphosphonate97%;Bromodifluoromethyl diethylphosphonate 97%;Diethyl (Bromodifluoromethyl)phosphonate >Diethyl [bromo(difluoro)methyl]phosphonate 97%
CBNumber:
CB8333674
???:
C5H10BrF2O3P
??? ??:
267.01
MOL ??:
65094-22-6.mol
MSDS ??:
SDS

Diethyl bromodifluoromethanephosphonate ??

?? ?
40-41 °C/0.05 mmHg (lit.)
??
1.503 g/mL at 25 °C (lit.)
???
n20/D 1.417(lit.)
???
>230 °F
?? ??
Keep in dark place,Inert atmosphere,Room temperature
???
?????, ???????? ???
??? ??
??
Specific Gravity
1.503
??
???
???
?? ???? ???? ??? ????.
BRN
1944045
InChI
InChI=1S/C5H10BrF2O3P/c1-3-10-12(9,11-4-2)5(6,7)8/h3-4H2,1-2H3
InChIKey
QRADKVYIJIAENZ-UHFFFAOYSA-N
SMILES
P(=O)(OCC)(OCC)C(F)(F)Br
CAS ??????
65094-22-6(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 21/22-36/38-38-36
????? 26-36/37/39-60-37-23
????(UN No.) 3278
WGK ?? 3
?? ?? ?? Irritant
TSCA No
?? ?? IRRITANT, IRRITANT-HARMFUL
???? III
HS ?? 29319090
???? ??? 10 - Combustible liquids
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P321 (…) ??? ???.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
NFPA 704
1
2 0

Diethyl bromodifluoromethanephosphonate MSDS


Diethyl bromodifluoromethanephosphonate

Diethyl bromodifluoromethanephosphonate C??? ??, ??, ??

??

Efficient difluoroalkylation of aryl boronic acids via palladium catalysis. Novel, moisture-stable bromodifluoromethylated phosphonate, ester, and amide. Efficient coupling with aryl boronic acids via Pd catalysis.

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 3437, 1984 DOI: 10.1021/jo00192a056

Diethyl bromodifluoromethanephosphonate ?? ?? ? ???

???

?? ??


Diethyl bromodifluoromethanephosphonate ?? ??

???( 253)?? ??
??? ?? ??? ?? ?? ? ??
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Diethyl bromodifluoromethanephosphonate ?? ??:

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