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97-41-6
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???(??):
?????????;?????????;????
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Ethyl chrysanthemumate
???(??):
ETHYL CHRYSANTHEMATE;Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate;PNP-α-D-Gal;Ethyl chrysant;Cyclopropaneca;TIMTEC-BB SBB007714;Ethyl chrisanthemate;Ethyl chrysanthemat.;Ethyl chrysanthemuma;Ethyl ChrsantheMuMate
CBNumber:
CB8400077
???:
C12H20O2
??? ??:
196.29
MOL ??:
97-41-6.mol
MSDS ??:
SDS

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?? ?
112 °C10 mm Hg(lit.)
??
0.906 g/mL at 25 °C(lit.)
???
n20/D 1.461(lit.)
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184 °F
?? ??
2-8°C
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?????(?? ???), ???(?? ???)
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????? ??? ? 10.00%. ?? ?? ???? ?? ??? ? ?? ???
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BRN
2045740
LogP
4.181 (est)
CAS ??????
97-41-6(CAS DataBase Reference)
NIST
Ethyl chrysanthemate(97-41-6)
EPA
Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, ethyl ester (97-41-6)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
????? 24/25
????(UN No.) UN1993
WGK ?? 2
RTECS ?? GZ1727000
TSCA TSCA listed
?? ?? 3
HS ?? 29162090
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H227 ??? ?? ??? ?? ?? 4 ?? P210, P280, P370+P378, P403+P235,P501
H303 ??? ??? ? ?? ?? ?? ?? - ?? ?? 5 P312
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P210 ?·???·??·????? ????? - ?? ???.
P261 ??·?·??·???·??·...·????? ??? ????.
P280 ????/???/???/?????? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P370+P378 ?? ? ?? ?? ?? (Section 5. ??, ??? ????? ??? ???)?(?) ?????.
P403+P235 ??? ? ?? ?? ???? ???? ?????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
1
0 0

?? ??????? MSDS


Ethyl 2,2-dimethyl-3-(1-isobutenyl)cyclopropane-1-carboxylate

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clear colorless to yellow liquid. Very slightly soluble in water, soluble in alcohol and oils. Powerful, winey-herbaccous, sweet and ethereal, very pleasant odor of intriguing complexity, and with a powerfully lifting minty undertone. The spicy-hcrbaccous, warm and almost green-floral notes resemble certain notes in the Jasmin complex.

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Ethyl Chrysanthemate is an organic building block used in the synthesis of various chemical compounds, such as insecticide, Resmethrin (R144685). It is used in the preparation of trans-norchrysanthemates and trans-norpyrethrates, having insecticidal activity.

Purification Methods

Purify the ester by vacuum distillation. The free trans-acid has m 54o (from EtOAc), and the free cis-acid has m 113-116o (from EtOAc). The 4-nitrophenyl ester has m 44-45o (from pet ether) [Campbell & Harper J Chem Soc 283 1945, IR: Allen et al. J Org Chem 22 1291 1957]. [Beilstein 9 II 45.]

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