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???-??-????? ????
???-??-????? ???? ??? ???
?? ??:
9011-11-4
???:
???-??-????? ????
???(??):
????-??-??????????;???-??-?????????;????-??-??????????(STYRENE-ALPHA-METHYLSTYRENECOPOLYMER);??(???-?-??-?????)
???:
POLY(STYRENE-CO-ALPHA-METHYLSTYRENE)
???(??):
Kristalex 5140;NORSOLENE W 140;Kristalex 5140SD;Styrene-α-methylstyrene polymer;poly(styrene-co-α-methylstyrene);Poly(styrene-co-α-methylstyrene);Styrol, a-methylstyrol, copolymer;POLY(STYRENE-CO-ALPHA-METHYLSTYRENE);Poly(styrene-co-α-methylstyrene);ethenyl-benzenpolymerwith(1-methylethenyl)benzene
CBNumber:
CB8401968
???:
(C9H10.C8H8)x
??? ??:
222.33
MOL ??:
9011-11-4.mol

???-??-????? ???? ??

???
171-188 °C
??
1.07 g/mL at 25 °C
???
????, ???? ? ??? ?????.
??? ??
solid
???
hydrocarbons, esters and ketones: soluble
water, alcohols and glycols: insoluble
??? ?? ??
???
???
InChI
1S/C9H10.C8H8/c1-8(2)9-6-4-3-5-7-9;1-2-8-6-4-3-5-7-8/h3-7H,1H2,2H3;2-7H,1H2
InChIKey
ZAKVZVDDGSFVRG-UHFFFAOYSA-N
SMILES
C=Cc1ccccc1.CC(=C)c2ccccc2
EPA
Benzene, ethenyl-, polymer with (1-methylethenyl)benzene (9011-11-4)

??

WGK ?? 3
TSCA TSCA listed
???? ??? 11 - Combustible Solids
???? ?? KE-13263

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Additive to sealants, caulks, adhesives, and coatings.

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a-Methylstyrene is obtained from benzene and propylene by the following route:

9011-11-4 synthesis


a-Methylstyrene is not readily polymerized by free radical initiators but it is susceptible to cationic polymerization. Polymerization can be effected, for example, in ethyl chloride at -130C with aluminium chloride but poly(a-methylstyrene) prepared in this manner is a clear brittle solid which has little commercial application. Polymers with much lower molecular weight (300-600) obtained by using alkaline earth catalysts, however, are viscous liquids and have found some use as plasticizers in surface coatings and adhesives.
Styrene-a-methylstyrene copolymers are marketed for extrusion and injection moulding. Compared to polystyrene, these copolymers have the advantage of higher softening points (104-106C); they too are transparent and colourless.

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