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4-Methylpyridazine

4-Methylpyridazine ??? ???
?? ??:
1120-88-3
???:
4-Methylpyridazine
???(??):
4-Methylpyridazin-3-aMine;4-Methy Pyridazine;4-METHYLPYRADIZINE;4-METHYLPYRIDAZINE;4-Methyl-1,2-diazine;4-Methylpyridazine>Pyridazine, 4-Methyl-;4-METHYLPYRIDAZINE 97%;4-Methylpyridazine,97%;4-Methylpyridazine ISO 9001:2015 REACH
CBNumber:
CB8468011
???:
C5H6N2
??? ??:
94.11
MOL ??:
1120-88-3.mol

4-Methylpyridazine ??

?? ?
98-100 °C/11 mmHg (lit.)
??
1.06 g/mL at 25 °C (lit.)
???
n20/D 1.521(lit.)
???
222 °F
?? ??
Sealed in dry,Room Temperature
?? ?? (pKa)
3.74±0.10(Predicted)
??? ??
??
??
?? ???
Specific Gravity
1.060
?? ??(λmax)
292nm(H2O)(lit.)
BRN
105689
InChI
InChI=1S/C5H6N2/c1-5-2-3-6-7-4-5/h2-4H,1H3
InChIKey
AIKUBOPKWKZULG-UHFFFAOYSA-N
SMILES
C1=NN=CC=C1C
CAS ??????
1120-88-3(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-37/39-36
WGK ?? 3
HS ?? 29339900
???? ??? 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
2 0

4-Methylpyridazine C??? ??, ??, ??

??? ??

Clear yellow liquid

??

4-Methylpyridazine was used in the preparation of series of novel pyridazine derivatives structurally related to bipyridine cardiotonics.

?? ??

4-methylpyridazine could be used as a starting material to synthesize a series of novel pyridazine derivatives structurally related to bipyridine cardiotonics[1].
Pyridazine (pydz) and 4-methylpyridazine (4Me-pydz) could form stable bis(monodentate) complexes of general formulae fac-[PtXMe3L2](X = Cl, Br or I) and fac-[ReX(CO)3L2](X = Cl, Br or I). These complexes in above-ambient temperature solutions exhibit 1,2-fluxional shifts between the nitrogen donor pairs of each ring[2].

?? ??

Products of reaction of methyl iodide with 4-methylpyridazine has been investigated by NMR spectra. Solvent free oxidation of 4-methylpyridazine by acetyl peroxyborate, peracetic acid and hydrogen peroxide has been reported.

4-Methylpyridazine ?? ?? ? ???

???

?? ??


4-Methylpyridazine ?? ??

???( 188)?? ??
??? ?? ??? ?? ?? ? ??
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4-Methylpyridazine ?? ??:

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