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4-???-2-??????

4-???-2-??????
4-???-2-?????? ??? ???
?? ??:
119-34-6
???:
4-???-2-??????
???(??):
4-???-2-??????;p-???-o-??????;p-???-o-??????(4-???-2-??????)
???:
4-Amino-2-nitrophenol
???(??):
Phenol, 4-amino-2-nitro-;ci76555;c.i.76555;fourrine57;nci-c03963;oxidationbase25;fourrinebrownpr;Aminonitrophenol;cioxidationbase25;fourrinebrownpropyl
CBNumber:
CB9120563
???:
C6H6N2O3
??? ??:
154.12
MOL ??:
119-34-6.mol
MSDS ??:
SDS

4-???-2-?????? ??

???
125-127 °C(lit.)
?? ?
322.46°C (rough estimate)
??
1.3617 (estimate)
???
1.6890 (rough estimate)
?? ??
2-8°C(protect from light)
?? ?? ??
76555
?? ?? (pKa)
7.90±0.14(Predicted)
??
Orange to Brown to Dark red
???
21 ºC?? <0.01g/100mL
BRN
1368435
Henry's Law Constant
4.5×106 mol/(m3Pa) at 25℃, HSDB (2015)
??? ?? ??
?? ??
??? ?? ??
4-Amino-2-nitrophenol (119-34-6)
InChI
1S/C6H6N2O3/c7-4-1-2-6(9)5(3-4)8(10)11/h1-3,9H,7H2
InChIKey
WHODQVWERNSQEO-UHFFFAOYSA-N
SMILES
Nc1ccc(O)c(c1)[N+]([O-])=O
CAS ??????
119-34-6(CAS DataBase Reference)
IARC
3 (Vol. 16, Sup 7) 1987
EPA
4-Amino-2-nitrophenol (119-34-6)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,T
?? ???? ?? 22-36/37/38-45
????? 22-24/25-37/39-26-53-45
????(UN No.) UN 2811 6.1/PG 3
WGK ?? 3
RTECS ?? SJ6303000
TSCA TSCA listed
HS ?? 29222990
???? ??? 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
?? ?? ??? 119-34-6(Hazardous Substances Data)
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? P264, P270, P301+P312, P330, P501
??????:
NFPA 704
1
2 0

4-???-2-?????? MSDS


4-Amino-2-nitrophenol

4-???-2-?????? C??? ??, ??, ??

??? ??

4-Amino-2-nitrophenol is a dark red crystalline or reddish-purple solid.

??

4-Amino-2-nitrophenol has been used in dyeing human hair and animal fur. The typical concentration in the “semipermanent” hair dyes was estimated to be on the order of 0.1–1.0%.

?? ??

Dark red plates, needles or reddish-purple powder. Melting point 125-127°C.

??? ?? ??

Sensitive to oxidation upon prolonged exposure to air. Insoluble in water.

?? ???

4-Amino-2-nitrophenol may react with strong oxidizing agents, strong bases, acid chlorides and acid anhydrides .

????

Flash point data for 4-Amino-2-nitrophenol are not available. 4-Amino-2-nitrophenol is probably combustible.

Safety Profile

Suspected carcinogen with experimental carcinogenic data. Very poisonous by intraperitoneal route. Moderately toxic by ingestion. A severe eye heated to decomposition it emits toxic fumes of NOx.

??? ??

In dye formulation for furs and hair

Carcinogenicity

Under the conditions of the bioassay, the compound was carcinogenic in male rats inducing transitional cell carcinomas of the urinary bladder (controls 0/15, lowdose 0/46, high dose 11/39). The same tumor was also observed in three dosed female rats and may have been associated with the administration of the chemical. No evidence of carcinogenic activity was found in the mice.

?? ??

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

? ???

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. It is unknown if this nitro compound is explosive; some are flammable and explosive, and the contact with alkali increases thermal sensitivity of these materials.

4-???-2-?????? ?? ?? ? ???

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?? ??


4-???-2-?????? ?? ??

???( 164)?? ??
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