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Diphenyldichloromethane

Diphenyldichloromethane ??? ???
?? ??:
2051-90-3
???:
Diphenyldichloromethane
???(??):
DICHLORODIPHENYLMETHANE;α,α-Dichlorodiphenylmethane;NSC 37425;Dichloroditane;DPM (Halocarbon);TIMTEC-BB SBB007844;Benzophenone chloride;BENZOPHENONE DICHLORIDE;DIPHENYLDICHLOROMETHANE;Dphenyl Dichloro Methane
CBNumber:
CB9133875
???:
C13H10Cl2
??? ??:
237.12
MOL ??:
2051-90-3.mol
MSDS ??:
SDS

Diphenyldichloromethane ??

???
190 °C (decomp)
?? ?
305 °C(lit.)
??
1.235 g/mL at 25 °C(lit.)
???
n20/D 1.605(lit.)
???
>230 °F
?? ??
Store below +30°C.
???
??(???), ????? (?? ???)
??? ??
??
??
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?(??), ???, ??, ??? ? ???? ?????.
BRN
1910601
InChI
InChI=1S/C13H10Cl2/c14-13(15,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChIKey
OPTDDWCXQQYKGU-UHFFFAOYSA-N
SMILES
C(C1=CC=CC=C1)(C1=CC=CC=C1)(Cl)Cl
CAS ??????
2051-90-3(CAS DataBase Reference)
EPA
Benzene, 1,1'-(dichloromethylene)bis- (2051-90-3)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C
?? ???? ?? 14-34-37
????? 26-36/37/39-45
????(UN No.) UN 3265 8/PG 2
WGK ?? 3
F ?????? 9-21
TSCA TSCA listed
?? ?? 8
???? II
HS ?? 29036990
???? ??? 8A - Combustible corrosive hazardous materials
Hazard Classifications Eye Dam. 1
Skin Corr. 1B
????(GHS): Corrosion (GHS05)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P363 ?? ??? ??? ??? ?????.
P405 ???? ?????.
NFPA 704
1
3 0
W

Diphenyldichloromethane C??? ??, ??, ??

??? ??

Diphenyldichloromethane is a clear light yellow liquid that is used as a precursor to other organic compounds.It is used in the synthesis of tetraphenylethylene, diphenylmethane imine hydrochloride and benzoic anhydride.

?? ??

Dichlorodiphenylmethane is synthesized by the condensation of benzene with carbon tetrachloride (Friedel-Crafts reaction). Add aluminum trichloride and 2/3 amount of anhydrous carbon tetrachloride into the reaction tank, cool to 10-15°C, add 1/12 amount of benzene for reaction, continue to cool to 5-10°C, add the remaining mixture of carbon tetrachloride and benzene dropwise, add after, react at 10°C for 3h.

Synthesis Reference(s)

The Journal of Organic Chemistry, 12, p. 807, 1947 DOI: 10.1021/jo01170a012

Diphenyldichloromethane ?? ?? ? ???

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Diphenyldichloromethane ?? ??

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Diphenyldichloromethane ?? ??:

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