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2,2-???????

2,2-???????
2,2-??????? ??? ???
?? ??:
77-76-9
???:
2,2-???????
???(??):
2,2-?????????;2,2-???????;2,2-???????
???:
2,2-Dimethoxypropane
???(??):
ACETONE DIMETHYL ACETAL;Propane, 2,2-dimethoxy-;2,2-Dimethyoxypropane;DMP)2,2-DiMethoxy;Acetone dimethyl acetal, DMP;NSC 62085;C.I. 77769;2,2-DIMETHOXYPROPANE;2,2-dimethoxy-propan;Dimolybdenum trioxide
CBNumber:
CB9373512
???:
C5H12O2
??? ??:
104.15
MOL ??:
77-76-9.mol
MSDS ??:
SDS

2,2-??????? ??

???
-47 °C
?? ?
83 °C (lit.)
??
0.847 g/mL at 25 °C (lit.)
?? ??
3.59 (vs air)
???
60 mm Hg ( 15.8 °C)
???
n20/D 1.378(lit.)
???
12 °F
?? ??
Store below +30°C.
???
180g/L
??? ??
??
Specific Gravity
0.852 (20/4℃)
??
???
????
31%, 58°F
???
18g/100mL(25℃)
BRN
635678
Henry's Law Constant
1.4×10-1 mol/(m3Pa) at 25℃, Ebert et al. (2023)
???
????. ???? ??? ???? ????. ??? ??? ??? ???? ??? ? ????. ??? ???? ??? ????? ??? ? ????. ?? ???? ???? ????.
InChI
1S/C5H12O2/c1-5(2,6-3)7-4/h1-4H3
InChIKey
HEWZVZIVELJPQZ-UHFFFAOYSA-N
SMILES
COC(C)(C)OC
????
21.46mN/m at 298.15K
CAS ??????
77-76-9(CAS DataBase Reference)
NIST
2,2-Dimethoxypropane(77-76-9)
EPA
Propane, 2,2-dimethoxy- (77-76-9)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,Xi
?? ???? ?? 11-36-36/37/38
????? 26-9-37/39-33-16-33,37/39
????(UN No.) UN 1993 3/PG 2
WGK ?? 2
F ?????? 10-21
TSCA TSCA listed
?? ?? 3
???? II
HS ?? 29110000
???? ??? 3 - Flammable liquids
Hazard Classifications Eye Irrit. 2
Flam. Liq. 2
?? LD50 orally in Rabbit: > 2260 mg/kg LD50 dermal Rat > 2100 mg/kg
???? ?? KE-11095
????(GHS): Flame (GHS02)Exclamation Mark (GHS07)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H225 ???? ?? ? ?? ??? ?? ?? 2 ?? P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
??????:
P210 ?·???·??·????? ????? - ?? ???.
P233 ??? ??? ?????. ??? ??? ? ?? ?? ??? ???? ?????.
P240 ??? ????? ?? ? ??????.
P241 ?? ??? ??[???/??/??/...]?(?) ?????.
P242 ???? ???? ?? ??? ?????
P243 ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
P370+P378 ?? ? ?? ?? ?? (Section 5. ??, ??? ????? ??? ???)?(?) ?????.
P403+P235 ??? ? ?? ?? ???? ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
3
2 0

2,2-??????? MSDS


Acetone dimethyl acetal

2,2-??????? C??? ??, ??, ??

???

?? 1, ?? 3, ??? 1.

??, ?? ? ??

?, ???, ??? ?? ?. ???? ??. ??? ??? ????? ??? ? ?? ??? ??? ??? ?. ?? ??? ?? ? ???? ??? ?? ??? ?. ???? ?????? ??? ??? ?. ??? ?? ?? ?? ????? ??.

??? ??

colourless liquid; B.P. 83℃. Ethereal odor. Soluble in alcohol, miscible with ess, oils and perfume chemicals. Stable when pure and at room temp. Decomposes into Acetone and Methanol during heating in presence of moisture or traces of mineral acid. Presumably not used in flavors. Rarely used in perfumes - for ethereal top-notes and "alcohol-like" effects. Produced synthetically via orthoformic ester or vinyl ether. Also from formiminomethyl-ether hydrochloride.

??

2,2-Dimethoxypropane(DMP) is used in histology and considered to be more efficient than ethanol for the dehydration of animal tissue.

?? ??

2,2-Dimethoxypropane is an organic compound, which may be used as a protecting agent in the process of the synthesis of structurally related alkaloids like narciclasine and lycoricidine using phenylbromide as the starting material.

2,2-??????? ?? ?? ? ???

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2,2-??????? ?? ??

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