p-?????
|
|
p-????? ??
- ???
- 42-45 °C
- ?? ?
- 220 °C (lit.)
- ??
- 1.306 g/mL at 25 °C (lit.)
- ?? ??
- 4.43 (vs air)
- ???
- 1 mm Hg ( 49.8 °C)
- ???
- 1.5579
- ???
- 240 °F
- ?? ??
- 2-8°C
- ???
- ???: ??? 50mg/mL, ????? ?? ?? ???, ?? ?? ??? ??? ? ???
- ?? ?? (pKa)
- 9.18(at 25℃)
- ??? ??
- ??? ??? ???
- ??
- ???? ?? ???
- ??
- ???
- ??????(pH)
- 5 (20°C in H2O)
- Odor Threshold
- 30 ppm
- ???
- ?? ?? 2.7g/100mL(20℃)
- ??
- Air Sensitive
- Merck
- 14,2154
- BRN
- 507004
- Henry's Law Constant
- 6.7×100 mol/(m3Pa) at 25℃, Chao et al. (2017)
- Dielectric constant
- 9.5（54.0℃）
- ???
- ????. ? ???, ? ???, ???, ?? ???? ????.
- ?? ??
- ??
??
??? ? ???
???(???)
- ??? ?? ??
- ??
- InChI
- 1S/C6H5ClO/c7-5-1-3-6(8)4-2-5/h1-4,8H
- InChIKey
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N
- SMILES
- Oc1ccc(Cl)cc1
- LogP
- 2.5 at 35℃
- CAS ??????
- 106-48-9(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xn,N | ||
|---|---|---|---|
| ?? ???? ?? | 20/21/22-51/53-50 | ||
| ????? | 28-61-28A-24/25-60-36/37 | ||
| ????(UN No.) | UN 2020 6.1/PG 3 | ||
| WGK ?? | 2 | ||
| RTECS ?? | SK2800000 | ||
| F ?????? | 10-23 | ||
| TSCA | TSCA listed | ||
| ?? ?? | 6.1 | ||
| ???? | III | ||
| HS ?? | 29081000 | ||
| ???? ??? | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
||
| Hazard Classifications | Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Aquatic Chronic 2 Eye Dam. 1 Skin Corr. 1B |
||
| ?? ?? ??? | 106-48-9(Hazardous Substances Data) | ||
| ?? | LD50 orally in rats: 0.67 g/kg (Deichmann) | ||
| ???? ?? | KE-05804 |
p-????? C??? ??, ??, ??
??? ??
off-white to light tan crystals or powder??
It is used as main raw material of compounding for medicine, dye, plastic and other industries. 4-Chlorophenol was used in visible-light-induced degradation of 4-chlorophenol in aqueous suspension of pure TiO2.??
ChEBI: A monochlorophenol substituted at the pare position by a chlorine atom.?? ??
White crystals with a strong phenol odor Slightly soluble to soluble in water, depending on the isomer, and denser than water. Noncombustible. Used as an intermediate in organic synthesis of dyes and drugs.??? ?? ??
Slightly soluble to soluble in water.?? ???
CHLOROPHENOLS, SOLID are incompatible with acid chlorides, acid anhydrides and oxidizing agents. Also incompatible with iron . Liquefy and darken in color at temperatures above 108°F.???
Toxic by skin absorption, inhalation, or ingestion; strong irritant to tissue.????
Inhalation causes headache, dizziness, weak pulse. Ingestion causes irritation of mouth and stomach; headache, dizziness, weak pulse. Contact with eyes causes severe irritation and burning. Contact with skin causes irritation and burn; if absorbed, causes same symptoms as inhalation.????
Special Hazards of Combustion Products: Toxic and irritating hydrogen chloride and chlorine gases may form in fires.Safety Profile
Poison by inhalation and intraperitoneal routes. Moderately toxic by ingestion, skin contact, and subcutaneous routes. A severe skin and eye irritant. Human systemic effects by inhalation: excitement, irritability. Mutation data reported. Combustible when exposed to heat or flame. To fight fire, use water, spray, mist, fog, foam, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROPHENOLS and CHLORIDES.??? ??
Monochlorophenols are used in the manufacture of fungicides, slimicides, bactericides, pesticides, herbicides, disinfectants, wood and glue preservatives; in the production of phenolic resins; in the extraction of certain minerals from coal; as a denaturant for ethanol; as an antiseptic; as a disinfectant, and others.?? ??
UN 2020 (solid); UN2021 (liquid) Chlorophenols, solid and liquid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.Purification Methods
Distil the phenol, then crystallise it from pet ether (b 40-60o) or hexane, and dry it under vacuum over P2O5 at room temperature. [Bernasconi & Paschalis J Am Chem Soc 108 2969 1986, Beilstein 6 IV 820.]? ???
May form explosive mixture with air. Contact with oxidizing agents can cause fire and explosion hazard. Heat produces hydrogen chloride and chlorine. Corrosive to aluminum, copper and other chemically active metals.??? ??
Incinerate in admixture with flammable solvent in furnace equipped with afterburner and scrubber.p-????? ?? ?? ? ???
???
?? ??
??????
ALUMINUM CLOFIBRATE
5-???-m-???-2,??,??'-???
2-(2-CHLOROETHOXY)-BENZENESULFONAMIDE
Triadimenol
4-??????
4-??????????
1-(4-??????)-3,3-????-1-(1H-1,2,4-????-1-?)-2- ???
2,6-???-4-?????
1,4-????????????
4-CHLOROPHENOXYACETYL CHLORIDE
2,2'-?????(4-?????)
4-????????? ??????
4-Mercaptophenol
3,4'-Dichlorodiphenyl ether
4-4'-??????????
4-(?????????)?????
Mefentrifluconazole
Azoic Diazo Component 33
1,4-????????????
p-????? ?? ??
???( 562)?? ??
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