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P-???? ?????

P-???? ?????
P-???? ????? ??? ???
?? ??:
540-23-8
???:
P-???? ?????
???(??):
P-?????????;P-?????????(P-TOLUIDINEHYDROCHLORIDE);??????????
???:
4-Methylaniline hydrochloride
???(??):
P-TOLUIDINE HYDROCHLORIDE;P-TOLUIDINE HCL;4-methylaniline HCL;Toluidinium chloride;P-TOLUIDINIUM CHLORIDE;p-Toluidine hydrochlori;4-methylaniliniumchloride;4-TOLUIDINE HYDROCHLORIDE;ρ-Toluidine hydrochliride;p-methylaniliniumchloride
CBNumber:
CB9689488
???:
C7H10ClN
??? ??:
143.61
MOL ??:
540-23-8.mol
MSDS ??:
SDS

P-???? ????? ??

???
243-245 °C(lit.)
??
1.193 g/cm3
?? ??
Store below +30°C.
???
?? ???
???
DMSO(??), ???(??)? ???
??? ??
powder to crystal
??
White to Gray to Red
BRN
3557540
???
???
InChI
1S/C7H9N.ClH/c1-6-2-4-7(8)5-3-6;/h2-5H,8H2,1H3;1H
InChIKey
JQKBUTDZZRGQDR-UHFFFAOYSA-N
SMILES
Cl[H].Cc1ccc(N)cc1
CAS ??????
540-23-8(CAS DataBase Reference)
EPA
p-Toluidine hydrochloride (540-23-8)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T,N
?? ???? ?? 23/24/25-36-40-43-50
????? 28-36/37-45-61
????(UN No.) UN 2811 6.1/PG 1
WGK ?? 3
RTECS ?? XU7525000
TSCA TSCA listed
?? ?? 6.1(a)
???? II
HS ?? 29214300
???? ??? 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Carc. 2
Eye Irrit. 2
Skin Sens. 1
?????? ??? 97-1-300
?? ? ???? ????: ????; ???(??)????: ????? ? ?? ? ? ? ??? 25% ?? ??? ???. ??, o-????(o-Toluidine)? ?? ?? 0.1% ?? ??? ???
????(GHS): Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H351 ?? ??? ??? ??? (????? ?? ???? ???? ???? ??? ?? ????? ??? ???? ??) ??? ?? ?? 2 ?? P201, P202, P281, P308+P313, P405,P501
H400 ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? P273, P391, P501
??????:
P201 ?? ? ?? ???? ?????.
P202 ?? ?? ?? ??? ?? ???? ??? ???? ???.
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P271 ?? ?? ??? ? ?? ???? ?????.
P272 ??? ??? ??? ??? ???? ???.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P308+P313 ?? ?? ??? ???? ???? ??· ??? ????.
P333+P313 ????? ?? ??? ???? ???? ??·??? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
P391 ???? ????.
P403+P233 ??? ??? ? ?? ?? ??? ???? ?????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
1
3 0

P-???? ????? C??? ??, ??, ??

??? ??

white to light beige crystalline powder, crystals

?? ??

Off-white to grayish-white crystals.

??? ?? ??

Water soluble. May be sensitive to moisture.

?? ???

4-Methylaniline hydrochloride reacts with oxidizing and alkali materials. .

????

Flash point data for 4-Methylaniline hydrochloride are not available, but 4-Methylaniline hydrochloride is probably combustible.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. Questionable carcinogen with experimental carcinogenic and tumorigenic data. When heated to decomposition it emits very toxic fumes of NOx and HCl. See also p-TOLUIDINE.

Purification Methods

Crystallise the salt from MeOH containing a few drops of conc HCl or aqueous EtOH. Dry it under vacuum over paraffin chips. [Beilstein 12 II 587, 12 III 2021, 12 IV 1869.]

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