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1054451-31-8

1054451-31-8 Structure

1054451-31-8 Structure
IdentificationBack Directory
[Name]

Boronic acid, B,B'-[(1,2-diphenyl-1,2-ethenediyl)di-4,1-phenylene]bis- 4,4'-(1,2-Diphenyl-1,2-ethenylene)diphenylboronic acid
[CAS]

1054451-31-8
[Synonyms]

TPE-BA
[(1,2-Diphenylethene-1,2-diyl)bis(4,1-phenylene)]diboronic acid
4,4'-(1,2-diphenylethene-1,2-diyl)bis(4,1-phenylene)diboronic acid
4,4'-(1,2-Diphenylethene-1,2-diyl)bis(1,4-phenylene)diboronic acid
4,4'-(1,2-diphenylethene-1,2-diyl)bis(1,4-phenylene)diboronic acid
(1,2-diphenylethene-1,2-diyl)bis(4,4'-phenylene)-1,1'-diboronic acid
Boronic acid, B,B'-[(1,2-diphenyl-1,2-ethenediyl)di-4,1-phenylene]bis-
Boronic acid, B,B'-[(1,2-diphenyl-1,2-ethenediyl)di-4,1-phenylene]bis- 4,4'-(1,2-Diphenyl-1,2-ethenylene)diphenylboronic acid
Boronic acid, B,B'-[(1,2-diphenyl-1,2-ethenediyl)di-4,1-phenylene]bis- 4,4'-(1,2-Diphenyl-1,2-ethenylene)diphenylboronic acid
[Molecular Formula]

C26H22B2O4
[MOL File]

1054451-31-8.mol
[Molecular Weight]

420.07
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C
[form ]

solid
[InChI]

1S/C26H22B2O4/c29-27(30)23-15-11-21(12-16-23)25(19-7-3-1-4-8-19)26(20-9-5-2-6-10-20)22-13-17-24(18-14-22)28(31)32/h1-18,29-32H/b26-25+
[InChIKey]

CFKHFTZRFSABDV-OCEACIFDSA-N
[SMILES]

OB(O)C(C=C1)=CC=C1/C(C2=CC=CC=C2)=C(C3=CC=C(B(O)O)C=C3)\C4=CC=CC=C4
Safety DataBack Directory
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

TPE-BA is an aggregation-induced emission (AIE) dye for use in Suzuki reaction and D-Glucose detection.
[General Description]

Aggregation-induced emission luminogens (AIEgens) such as tetraphenylethene (TPE) functionalized with boronic acids form luminogen (TPE-BA). TPE-BA can form oligoboronates with D-glucose. Other sugars also form monoadduct with TPE-BA, but once such a complex is formed there is no more cis-diol that allows the oligomerization reaction to proceed, resulting in a very low emission intensity. Thus, TPE-BA could serve as a glucose-specific probe.
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