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2375242-78-5

2375242-78-5 Structure

2375242-78-5 Structure
IdentificationBack Directory
[Name]

Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1)
[CAS]

2375242-78-5
[Synonyms]

Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1)
[Molecular Formula]

C38H44ClNO5PPdS.Na
[MOL File]

2375242-78-5.mol
[Molecular Weight]

822.67
Chemical PropertiesBack Directory
[Melting point ]

193-194 °C (decomposition)
[form ]

solid
[color ]

Light brown to brown
Hazard InformationBack Directory
[Uses]

sSPhos Pd G2 can be used as a water-soluble Pd-precatalyst in:
  • DNA-compatible Suzuki-Miyaura reaction between DNA-linked aryl halides and various boronic acids/esters including heteroaryl boronates.
  • DNA-compatible hydroxycarbonylation reactions.
  • The cross-coupling reaction between boronic ester and brominated cyclic nucleotide to synthesize cyclic adenosine and guanosine monophosphate in the presence of potassium phosphate and hydrochloric acid.
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
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