| Identification | Back Directory | [Name]
IODO(TRIETHYL PHOSPHITE)COPPER(I), 97% | [CAS]
51717-23-8 | [Synonyms]
Copper(I) iodide-triethyl phosphite
(triethyl phosphite)copper(I) iodide
IODO(TRIETHYL PHOSPHITE)COPPER(I), 97% | [Molecular Formula]
C6H15CuIO3P | [MDL Number]
MFCD00074947 | [MOL File]
51717-23-8.mol | [Molecular Weight]
356.606 |
| Chemical Properties | Back Directory | [Melting point ]
110-116°C | [solubility ]
sol benzene, cyclohexane, bromoform, acetone, ether, and THF; also sol warm petroleum ether | [form ]
solid | [InChI]
1S/C6H15O3P.Cu.HI/c1-4-7-10(8-5-2)9-6-3;;/h4-6H2,1-3H3;;1H/q;+1;/p-1 | [InChIKey]
IVPQRWLSGJFSTC-UHFFFAOYSA-M | [SMILES]
[Cu]I.CCOP(OCC)OCC |
| Hazard Information | Back Directory | [Uses]
Iodo(triethyl Phosphite)copper(I) is a catalyst for organic synthesis. | [Synthesis Reference(s)]
1.Nishizawa, Y. BCJ 1961, 34, 1170.
| [reaction suitability]
core: copper
reagent type: catalyst | [Synthesis]
Iodo(triethyl phosphite)copper(I) is synthesized in 88.6% yield by addition of Copper(I) Iodide to a solution of Triethyl Phosphite in benzene; the mixture is stirred and heated until the CuI dissolves; the complex is obtained upon evaporation of the solvent under reduced pressure.1
| [Purification Methods]
Iodo(triethyl Phosphite)copper(I) is recrystallized from petroleum ether.
| [Precautions]
Iodo(triethyl Phosphite)copper(I) is irritant; use in a fume hood; mechanical exhaust required; harmful by inhalation, ingestion, or skin absorption; incompatible with strong oxidizing agents; sensitive to air, moisture, and light; store under N2 in a cool dry place.
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