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6882-09-3

6882-09-3 Structure

6882-09-3 Structure
IdentificationBack Directory
[Name]

UNDULATINE
[CAS]

6882-09-3
[Synonyms]

UNDULATINE
1β,2β-Epoxy-3α,7-dimethoxycrinan
[Molecular Formula]

C18H21NO5
[MOL File]

6882-09-3.mol
[Molecular Weight]

331.363
Chemical PropertiesBack Directory
[Melting point ]

151-2°C
Hazard InformationBack Directory
[Description]

This alkaloid occurs in the bulbs of Nerine fiexuosa alba and forms colourless needles from EtOH or Et2O. It is laevorotatory having [α]25589 - 31.8° (c 0.99, EtOH) or - 32.3° (c 0.65, EtOH). The perchlorate forms colourless prisms, m.p. 229.5-230.5°C; [α]23589 - 22° (c 1.06, EtOH) and the picrate is obtained as yellow needles, m.p. 226-7°C (dec.). Reduction with LiAlH4 gives the dihydro derivative which forms colourless crystals from AcOEt, m.p. 250-251.5°C; [α]25D - 39° (c 2.13, CHCI3 ).
[References]

Wemhoff, Wildman.,!. Amer. Chem. Soc., 82, 1472 (1960)
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