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705945-68-2

705945-68-2 Structure

705945-68-2 Structure
IdentificationBack Directory
[Name]

(S)-TCFP-RH
[CAS]

705945-68-2
[Synonyms]

(S)-TCFP-RH
R[Rh(cod)TCFP]BF4
(S)-[Rh COD TCFP]BF4
(S)-[Rh COD TCFP]BF4, Rh 18.4%
(S)-(+)-T-BUTYLMETHYL(DI-T-BUTYLPHOSPHINOMETHYL)PHOSPHINO(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-eta4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
(S)-(+)-t-ButylMethyl(di-t-butylphosphinoMethyl)phosphino(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,97% (S)-TCFP-Rh
(S)-(+)-t-Butylmethyl(di-t-butylphosphinomethyl)phosphino(1,5-cyclooctadiene)
rhodium(I) tetrafluoroborate, min. 97% (S)-TCFP-Rh
[Molecular Formula]

C14H32P2.C8H12.BF4.Rh
[MDL Number]

MFCD11973806
[MOL File]

705945-68-2.mol
[Molecular Weight]

560.251
Chemical PropertiesBack Directory
[Melting point ]

171-177 °C
[storage temp. ]

2-8°C
[form ]

solid
Hazard InformationBack Directory
[Uses]

R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used:
  • In the asymmetric reduction of amines, ketones and unsaturated acids.
  • As a hydrogenation catalyst in the preparation of diastereomers of trifluorovaline.
  • As a catalyst in the olefin asymmetric hydrogenation.

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