ChemicalBook--->CAS DataBase List--->867-27-6

867-27-6

867-27-6 Structure

867-27-6 Structure
IdentificationBack Directory
[Name]

Metasystox
[CAS]

867-27-6
[Synonyms]

BAY-15203
ENT-18862
Metasystox
methyl systox
Demeton methyl
emeton-O-methyl
O-Methyldemeton
demeton-O-methyl
Methyl demeton-O
METHYLMERCAPTOPHOS
Demeton methyl Solution, 100ppm
Demeton methyl Solution, 1000ppm
2-(ethylthio)ethoxy-dimethoxy-thioxo-phosphorane
O-2-ethylthioethyl O,O-dimethyl phosphorothioate
O,O-DIMETHYLO-ETHYL-2-THIOETHYLETHYLTHIONOPHOSPHATE
Phosphorothioic acid O,O-dimethyl O-[2-(ethylthio)ethyl]
2-ethylsulfanylethoxy-dimethoxy-sulfanylidene-$l^{5}-phosphane
Phosphorothioic acid, O-[2-(ethylthio)ethyl] O,O-dimethyl ester
demeton-O-methyl (ISO) O-2-ethylthioethyl O,O-dimethyl phosphorothioate
[EINECS(EC#)]

212-758-1
[Molecular Formula]

C6H15O3PS2
[MOL File]

867-27-6.mol
[Molecular Weight]

230.285
Chemical PropertiesBack Directory
[Melting point ]

<25 °C
[Boiling point ]

bp0.15 74°
[density ]

d420 1.190
[refractive index ]

nD20 1.5063
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Oil
[color ]

Colourless
[Henry's Law Constant]

3.2×100 mol/(m3Pa) at 25℃, Ebert et al. (2023)
[EPA Substance Registry System]

Demeton-O-methyl (867-27-6)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

25
[Safety Statements ]

24-36/37-45
[RIDADR ]

3018
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Safety Profile]

Poison by ingestion, skin contact, inhalation, and intravenous routes. Experimental teratogenic and reproductive effects. When heated to decomposition it emits very toxic fumes of POx and SOx. See also DEMETON-0 + DEMETON-S and other DEMETON entries.
Hazard InformationBack Directory
[Description]

Demeton-O-methyl is an organophosphate insecticide. Other than having a moderate aqueous solubility, very little data is available regarding its environmental fate. It is moderately toxic to honeybees and earthworms. Other ecotoxicity data is missing. Demeton-O-methyl is an acetylcholinesterase inhibitor and a neurotoxin. It is also an irritant.
[Uses]

Demeton Methyl is an organophosphorus pesticides.
[Production Methods]

Demeton-O-methyl is commercially produced through esterification of thiophosphoric acid derivatives with methanol. In industrial settings, demeton-O-methyl is synthesised by reacting O,O-dimethyl phosphorochloridothioate with 2-(methylthio)ethanol under controlled conditions.
[Mechanism of action]

Systemic with contact and stomach action. Acetylcholinesterase (AChE) inhibitor.
[Pesticide Type]

Insecticide; Acaricide
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