5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
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- CAS-Nr.
- 16456-81-8
- Englisch Name:
- 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
- Synonyma:
- Fe(TPP)Cl;MESO-TETRAPHENYLPORPHYRIN IRON(III) CHLORIDE;DK7596;IRON TPP;RARECHEM AS SA 0004;PROTOPORPHYRIN IX FE(III) CHLORIDE;TETRAPHENYLPORPHYRIN IRON III CHLORIDE;IRON (III) TETRAPHENYLPORPHINE CHLORIDE;Iron(III) Tetraphenylporphyrin Chloride;Fe(III)meso-Tetraphenylporphine Chloride
- CBNumber:
- CB0116059
- Summenformel:
- C44H28ClFeN4
- Molgewicht:
- 704.03
- MOL-Datei:
- 16456-81-8.mol
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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Eigenschaften
- Schmelzpunkt:
- 300 °C
- storage temp.
- Inert atmosphere,Room Temperature
- Aggregatzustand
- crystal
- Farbe
- purple
- Wasserl?slichkeit
- Insoluble in water.
- maximale Wellenl?nge (λmax)
- 418 nm
- Stabilit?t:
- Stable. Incompatible with strong oxidizing agents, strong acids.
- InChIKey
- ZDYSAMCSFRQDMN-XBZZRTMISA-M
- SMILES
- [Cl-][Fe+3]123N4C5C=CC=4C(C4C=CC=CC=4)=C4C=CC(=C(C6C=CC=CC=6)C6C=CC(=C(C7C=CC=CC=7)C7=CC=C(C=5C5C=CC=CC=5)[N-]17)N2=6)[N-]34
- CAS Datenbank
- 16456-81-8
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| S-S?tze: |
22-24/25 |
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| WGK Germany |
3 |
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| HS Code |
29349990 |
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| Speicherklasse |
11 - Combustible Solids |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitssch?dlich bei Verschlucken. |
Akute Toxizit?t oral |
Kategorie 4 |
Warnung |
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P264, P270, P301+P312, P330, P501 |
| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
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P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
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P264, P280, P305+P351+P338,P337+P313P |
| H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizit?t (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
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| Sicherheit |
| P261 |
Einatmen von Staub vermeiden. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
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5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Chemische Eigenschaften,Einsatz,Produktion Methoden
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
dark red or purple powder
Verwenden
Iron(III) meso-tetraphenylporphine chloride is used catalyzing reagent for silylation reactions.
l?uterung methode
Purify it by extraction from a thimble (Soxhlet) with CHCl3. Concentrate the extract to ca 10mL and add ca 80mL of hot MeOH. Dark blue crystals separate on cooling. It can be recrystallised several times from CHCl3/MeOH. Avoid prolonged heating. It is quite soluble in organic solvents but insoluble in pet ether. [Rothemund & Manotti J Am Chem Soc 70 1808 1948, UV: Dorough et al. J Am Chem Soc 73 4315 1951, Beilstein 26 III 1960.]
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 137)Lieferanten
16456-81-8()Verwandte Suche:
5,10,15,20-Tetraphenyl-21H,23H-porphin
3,3'-(3,7,12,17-Tetramethyl-8,13-divinylporphin-2,18-diyl)di(propionsure)
- 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
- 5,10,15,20-TETRAPHENYL-21H,23H-PORPHYRIN IRON(III) CHLORIDE
- MESO-TETRAPHENYLPORPHYRIN IRON(III) CHLORIDE COMPLEX
- IRON TPP
- IRON (III) MESO-TETRAPHENYLPORPHINE CHLORIDE
- IRON (III) TETRAPHENYLPORPHINE CHLORIDE
- RARECHEM AS SA 0004
- TETRAPHENYLPORPHYRIN IRON III CHLORIDE
- PROTOPORPHYRIN IX FE(III) CHLORIDE
- Iron,chloro[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N) di-(Fe-21,N22,N23,N24]-(SP-5-12)-
- chloro(5,10,15,20-tetraphenyl)porphyrinatoiron(III)
- Iron(III) meso-Tetraphenylporhpine Chloride
- 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE, SYNTHETIC
- 5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride,meso-Tetraphenylporphyrin iron(III) chloride
- Fe(III) meso-Tetraphenylporphine Chloride (contains 1-3% chlorin)
- 5,10,15,20-Tetraphenyl-21H,23H-porphine iron(Ⅲ) chloride
- 5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride >=94% (HPLC)
- IRON(3+) ION TETRAPHENYLPORPHYRIN TRICHLORIDE
- Iron(III) Tetraphenylporphyrin Chloride
- 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE ISO 9001：2015 REACH
- Iron,chloro[5,?10,15,20-tetraphenyl-21H,23H-porphinato(2-)-?κN21,κN22,κN23,κN24]-,(SP-5-2)
- 21H,23H-Porphine, 5,10,15,20-tetraphenyl-, iron complex
- 5,1,15,2-Tetraphenyl-21H,23H-porphine iron(III) chloride
- 16456-81-8 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
- MESO-TETRAPHENYLPORPHYRIN IRON(III) CHLORIDE
- DK7596
- Fe(III)meso-Tetraphenylporphine Chloride
- 5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride
- Fe(TPP)Cl
- 16456-81-8
- FeC44H28N4Cl
- C44H28ClFeN4
- Catalysis and Inorganic Chemistry
- metal porphine (porphyrin) complex
