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laurotetanine

laurotetanine Struktur
128-76-7
CAS-Nr.
128-76-7
Englisch Name:
laurotetanine
Synonyma:
Litsoeine;NSC106610;NSC-106610;NSC 106610;Laurotetanin;laurotetanine;(6aS)-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-4H-dibenzo[de,g]quinolin-9-ol;[S,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-4H-dibenzo[de,g]quinolin-9-ol;4H-Dibenzo[de,g]quinolin-9-ol, 5,6,6a,7-tetrahydro-1,2,10-trimethoxy-, (6aS)-
CBNumber:
CB01339347
Summenformel:
C19H21NO4
Molgewicht:
327.37
MOL-Datei:
128-76-7.mol

laurotetanine Eigenschaften

Schmelzpunkt:
125°C
Siedepunkt:
465.27°C (rough estimate)
Dichte
1.2223 (rough estimate)
Brechungsindex
1.5000 (estimate)
pka
9.76±0.20(Predicted)

Sicherheit

laurotetanine Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

The noraporphine alkaloid was first isolated by Greshoff from Litsea chrysocorna and subsequently from other species of Lauraceae including L. citrata and L. cubeba. When freshly crystallized from Me2 CO it yields colourless crystals but these become yellow in air. The alkaloid behaves as a phenolic base giving salts with mineral acids which all contain H20 of crystallization. The picrate monohydrate has m.p. 1480 C, the dibenzoyl derivative, m.p. 169-1700 C and the phenylthiocarbamide, m.p. 211-2°C. Three methoxyl groups, an imino group and a phenolic hydroxyl group are present, the latter giving the O-methyl ether which is an amorphous powder but yields a crystalline hydrochloride, m.p. 245°C; an oxalate, m.p. 233°C and the thiocarbamide, m.p. 154-5°C. The Nmethyl derivative (q.v.) is found naturally in Peurnus boldus and the O,Ndimethyl derivative is glaucine. The structure has been determined from chemical degradation and synthesis.

Einzelnachweise

Greshoff., Ber., 23,3537 (1890)
Filippo., Arch. Pharm., 236, 601 (1898)
Gorter., Bull. Jard. bot. Buitenzorg., 3, 180 (1921)
Barger, Silberschmidt.,J. Chem. Soc., 2919 (1928)
Barger et al., Ber., 66, 450 (1933)
Ruegger., Helv. Chim. Acta, 42,754 (1959)
Kikkawa.,J. Pharm. Soc., Japan, 79,83,425 (1959)

laurotetanine Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


laurotetanine Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 9)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
TargetMol Chemicals Inc.
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BioBioPha Co., Ltd. 0871-65217109
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Shanghai Binsui Biotechnology Co., Ltd. 18301908279 18301908279;
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TargetMol Chemicals Inc. 15002134094
marketing@targetmol.cn China 29867 58
Sichuan BioCrick Biotech Co., Ltd 28-86-28-8543-3893 13260669172
sales@biocrick.com China 5020 58
Chengdu DeSiTe Biological Technology Co., Ltd 17308096051 17308096051
3001048290@qq.com China 4200 58

128-76-7()Verwandte Suche:


  • laurotetanine
  • (6aS)-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-4H-dibenzo[de,g]quinolin-9-ol
  • [S,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-4H-dibenzo[de,g]quinolin-9-ol
  • Litsoeine
  • Laurotetanin
  • NSC 106610
  • NSC106610
  • NSC-106610
  • 4H-Dibenzo[de,g]quinolin-9-ol, 5,6,6a,7-tetrahydro-1,2,10-trimethoxy-, (6aS)-
  • 128-76-7
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