2,2'-Furoin
|
|
|
- CAS-Nr.
- 552-86-3
- Bezeichnung:
- 2,2'-Furoin
- Englisch Name:
- 2,2'-Furoin
- Synonyma:
- FUROIN;1,2-di(furan-2-yl)-2-hydroxyethan-1-one;Furoin>a,a-Furoin;Furoin,98%;Furoin 98%;alpha-furoi;2,2'-Furoin;2,2'-Furoin;ALPHA-FUROIN
- CBNumber:
- CB0164010
- Summenformel:
- C10H8O4
- Molgewicht:
- 192.17
- MOL-Datei:
- 552-86-3.mol
|
2,2'-Furoin Eigenschaften
- Schmelzpunkt:
- 134-137 °C(lit.)
- Siedepunkt:
- 248.14°C (rough estimate)
- Dichte
- 1.0825 (rough estimate)
- Brechungsindex
- 1.4440 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- L?slichkeit
- acetone: soluble0.25g/10 mL, clear, colorless to deep brown-yellow
- Aggregatzustand
- powder to crystal
- pka
- 11.62±0.20(Predicted)
- Farbe
- White to Light yellow to Light orange
- BRN
- 383995
- InChI
- InChI=1S/C10H8O4/c11-9(7-3-1-5-13-7)10(12)8-4-2-6-14-8/h1-6,9,11H
- InChIKey
- MIJRFWVFNKQQDK-UHFFFAOYSA-N
- SMILES
- C(=O)(C1=CC=CO1)C(C1=CC=CO1)O
- CAS Datenbank
- 552-86-3(CAS DataBase Reference)
- NIST chemische Informationen
- Ethanone, 1,2-di-2-furanyl-2-hydroxy-(552-86-3)
- EPA chemische Informationen
- Ethanone, 1,2-di-2-furanyl-2-hydroxy- (552-86-3)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Bildanzeige (GHS) |
|
| Alarmwort |
Warnung
|
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitssch?dlich bei Verschlucken. |
Akute Toxizit?t oral |
Kategorie 4 |
Warnung |
|
P264, P270, P301+P312, P330, P501 |
| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
|
P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
|
P264, P280, P305+P351+P338,P337+P313P |
| H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizit?t (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
|
|
|
| Sicherheit |
| P261 |
Einatmen von Staub vermeiden. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
|
2,2'-Furoin Chemische Eigenschaften,Einsatz,Produktion Methoden
Chemische Eigenschaften
LIGHT YELLOW TO LIGHT BROWN AMORPHOUS POWDER
Verwenden
Furoin was used as fluorogenic reagent for the selective and sensitive liquid chromatographic determination of various guanidines.
synthetische
2,2'-Furoin is prepared by the condensation of furfural with benzoin under the catalysis of potassium cyanide. 8L of water, 3L of ethanol, and 4kg of furfural were heated to 60-70°C on a water bath, and a solution of 200g potassium cyanide dissolved in 600Chemicalbookml of water was slowly added under stirring. The reaction exotherm automatically heated up to 80-90 ° C, and crystals were precipitated later. After standing, filter, wash the crystals with water and methanol until the washing is colorless, and recrystallize with ethanol, which is the finished product of bran coupler.
l?uterung methode
It crystallises from MeOH (charcoal) and distils in a vacuum. [Hartman & Dickey J Am Chem Soc 55 1228 1933.] The (-)-enantiomer crystallises from toluene or EtOH with m 131-131o, and [] 20 -4.9o (dioxane) [Neuberg et al. Arch Biochem 1 393 1943, Beilstein 19 H 204, 19 I 710, 19 II 224, 19 III/IV 2543.]
2,2'-Furoin Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
2,2'-Furoin Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 151)Lieferanten
552-86-3(2,2'-Furoin)Verwandte Suche:
- 1,2-Di(2-furyl)-2-hydroxyethanone
- 1,2-di-2-furanyl-2-hydroxy-ethanon
- 1,2-di-2-furanyl-2-hydroxyethanone
- 1,2-di-2-furyl-2-hydroxy-ethanon
- Ethanone, 1,2-di-2-furyl-2-hydroxy-
- furoylfurylcarbinol
- Furoylfu-rylcarbinol
- Ketone, 2-furyl alpha-hydroxyfurfuryl
- ketone,2-furylalpha-hydroxyfurfuryl
- ALPHA-FUROIN
- 1,2-DI(2-FURYL)-2-HYDROXYETHAN-1-ONE
- alpha-Furoin,98+%
- furylfuroylcarbinol
- a,a-Furoin
- alpha-furoi
- Furoin, GC 98+%
- 1,2-Bis(furan-2-yl)-2-hydroxyethan-1-one
- alpha-Hydroxyketone
- Ethanone, 1,2-di-2-furanyl-2-hydroxy-
- 1,2-Di-2-furanyl-2-hydroxyethan-1-one
- Furoin,98%
- Furoin 98%
- 1,2-Di(furan-2-yl)
- -2-hydroxyethanone
- Furoin≥ 98% (GC)
- 1,2-di(furan-2-yl)-2-
hydroxyethanone
- 1,2-Bis(FuraN-2-Yl)-2-Hydroxyethanone
- Furoin>
- 552-86-3 2,2'-Furoin
- EGP437. Dex-Phos
- Furfuryl cause
- Furoin (6CI, 7CI, 8CI)
- Ascorbic Acid Impurity 33
- FUROIN (1,2-di(2-furyl)-2-hydroxyethan-1-one)
- 2,2'-Furoin
- 1,2-Bis (furan-2-yl) -2-hydroxy-1-ethanone
- 2,2'-Furoin
- 1,2-di(furan-2-yl)-2-hydroxyethan-1-one
- FUROIN
- 552-86-3
- C4H3OCHOHCOC4H3O
- Building Blocks
- Heterocyclic Building Blocks
- Furans
- Bioactive Small Molecules
- Building Blocks
- C8 to C11
- Cell Biology
- Chemical Synthesis
- F
- Heterocyclic Building Blocks
- Pharmaceutical Intermediates
- Building Blocks
- Furans
- Heterocyclic Building Blocks
