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Digalliumtrioxid

Gallium(III) oxide Struktur
12024-21-4
CAS-Nr.
12024-21-4
Bezeichnung:
Digalliumtrioxid
Englisch Name:
Gallium(III) oxide
Synonyma:
GALLIUM OXIDE;galliumtrioxide;Ga2-O3;Gallia;β-Ga2O3;Gallic oxide;ium(III) oxide;GalliuM(Ⅵ) oxide;Gallium(Ⅲ) oxide;GALLIUM(+3)OXIDE
CBNumber:
CB0268996
Summenformel:
Ga2O3
Molgewicht:
187.44
MOL-Datei:
12024-21-4.mol

Digalliumtrioxid Eigenschaften

Schmelzpunkt:
1740 °C
Dichte
6.44 g/mL at 25 °C
Brechungsindex
1.92
storage temp. 
Sealed in dry,Room Temperature
L?slichkeit
soluble in hot acid solutions
Aggregatzustand
Powder or Lump
Wichte
6.44
Farbe
White
Wasserl?slichkeit
Soluble in acids. Insoluble in water
Spezifische W?rmekapazit?t
Cp(crystal): 0.49 J/(g·K), at 25℃
Crystal Structure
Corundum type
crystal system
Three sides
Merck 
14,4346
Space group
R3c
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.498250.498251.343390901200.2888
Stabilit?t:
Stable. Incompatible with magnesium.
InChIKey
QZQVBEXLDFYHSR-UHFFFAOYSA-N
CAS Datenbank
12024-21-4(CAS DataBase Reference)
EPA chemische Informationen
Gallium trioxide (12024-21-4)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
S-S?tze: 24/25
WGK Germany  2
RTECS-Nr. LW9650000
TSCA  TSCA listed
HS Code  28259090
Toxizit?t mammal (species unspecified),LDLo,intraperitoneal,10gm/kg (10000mg/kg),BEHAVIORAL: EXCITEMENTLUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSIONBEHAVIORAL: ATAXIA,Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 31(6), Pg. 58, 1987.
Bildanzeige (GHS) Exclamation Mark (GHS07)
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung
Sicherheit
P261 Einatmen von Staub vermeiden.
P271 Nur im Freien oder in gut belüfteten R?umen verwenden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

Digalliumtrioxid Chemische Eigenschaften,Einsatz,Produktion Methoden

S-S?tze Betriebsanweisung:

S24/25:Berührung mit den Augen und der Haut vermeiden.

Beschreibung

Gallium(III) oxide (Ga2O3) is a wide band gap semiconductor that belongs to a family of transparent semiconducting oxides (TSO). It can form different polymorphs such as α-,β-, γ-, δ-, and ε-. Polycrystalline and nanocrystalline Ga2O3 can be prepared using several methods such as chemical vapor deposition, thermal vaporization, and sublimation, molecular beam epitaxy, melt growth, etc. It is widely used as a functional material in various applications including optoelectronics, chemical sensors, catalysis, semiconductor devices, field-effect transistors, and many others.

Chemische Eigenschaften

white odourless powder

Verwenden

In semiconductors; gas sensing; catalysis. Nanostructures as blue and UV light emitters in optoelectronic device applications.
Gallium(III) oxide has been reported in applications in lasers, phosphors, and luminescent materials. Monoclinic ß-Ga2O3 is used in gas sensors and luminescent phosphors and can be applied to dielectric coatings for solar cells. This stable oxide has also shown potential for deep-ultraviolet transparent conductive oxides, and transistor applications. Thin Ga2O3 films are of commercial interest as gas sensitive materials. ß-Gallium(III) oxide is used in the production of Ga2O3-Al2O3 catalyst.

Vorbereitung Methode

Gallium oxide is formed during the annealing or heating of semiconductors containing gallium in the microelectronics industry.

Allgemeine Beschreibung

Odorless fine white powder. Insoluble in water.

Air & Water Reaktionen

Insoluble in water.

Reaktivit?t anzeigen

GALLIUM(III) OXIDE may react with acids. Heating (to 1292° F) with magnesium causes a violent reduction to metallic slate.

Health Hazard

SYMPTOMS: Symptoms of exposure to GALLIUM(III) OXIDE include reduction of red blood cells and platelets, anemia, skin rash and nausea.

Brandgefahr

Flash point data for GALLIUM(III) OXIDE are not available; however, GALLIUM(III) OXIDE is probably combustible.

Einzelnachweise

Highly selective and rapid enrichment of phosphorylated peptides using gallium oxide‐coated magnetic microspheres for MALDI‐TOF‐MS and nano‐LC‐ESI‐MS/MS/MS analysis DOI:10.1002/PMIC.200700454
Development of gallium oxide power devices (Phys. Status Solidi A 1∕2014) DOI:10.1002/PSSA.201470201
Synthesis and characterization of morphologically different high purity gallium oxide nanopowders DOI:10.1007/S10853-007-1869-2
Structure, Morphology, and Optical Properties of Amorphous and Nanocrystalline Gallium Oxide Thin Films DOI:10.1021/JP311300E
Electrical and optical properties of deep ultraviolet transparent conductive Ga2O3/ITO films by magnetron sputtering DOI:10.1088/1674-4926/31/10/103001
Patty's Toxicology, 6 Volume Set, 6th Edition

Digalliumtrioxid Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Digalliumtrioxid Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 300)Lieferanten
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12024-21-4(Digalliumtrioxid)Verwandte Suche:


  • GalliuM(III) oxide, 99.99+%, (trace Metal basis)
  • GALLIUM SESQUIOXIDE
  • GALLIUM(III) OXIDE
  • GALLIUM(+3)OXIDE
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  • GALLIUM OXIDE
  • 12024-21-4
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  • Catalysis and Inorganic Chemistry
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  • Oxides
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