Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
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- CAS-Nr.
- 172222-30-9
- Englisch Name:
- Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
- Synonyma:
- Grubbs;GRUBBS CATALYST;Grubbs 1st;Grubbs I;Grubbs 1st Catalyst;Bis(tricyclohexylphosphine)benzylidine ruthenium (IV) dichloride;Grubbs Gen.1;GRUBB'S CATALYST;GRUBBS CATALYST, 1ST GENERATION;bis(tricyclohexylphosphine)benzylidine ruthenium dichloride
- CBNumber:
- CB0296067
- Summenformel:
- C43H73Cl2P2Ru
- Molgewicht:
- 823.96
- MOL-Datei:
- 172222-30-9.mol
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Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium Eigenschaften
- Schmelzpunkt:
- 153 °C (dec.)(lit.)
- storage temp.
- 2-8°C
- L?slichkeit
- Chloroform (Slightly), Dichloromethane (Sparingly)
- Aggregatzustand
- solid
- Farbe
- Purple
- Merck
- 13,4565
- InChI
- InChI=1S/2C18H33P.C7H5.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h2*16-18H,1-15H2;2-6H;2*1H;/q;;-2;;;+2
- InChIKey
- PNPBGYBHLCEVMK-UHFFFAOYSA-L
- SMILES
- [Ru+4]([Cl-])([Cl-])(=[C-2]C1C=CC=CC=1)(P(C1CCCCC1)(C1CCCCC1)C1CCCCC1)P(C1CCCCC1)(C1CCCCC1)C1CCCCC1
- CAS Datenbank
- 172222-30-9
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Kennzeichnung gef?hrlicher |
Xi,F |
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| R-S?tze: |
36/37/38-11 |
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| S-S?tze: |
26-36 |
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| RIDADR |
1325 |
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| WGK Germany |
3 |
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| F |
10-23 |
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| HazardClass |
4.1 |
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| PackingGroup |
Ⅱ |
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| HS Code |
28439000 |
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| Speicherklasse |
4.1B - Flammable solid hazardous materials |
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| Hazard Classifications |
Flam. Sol. 2 |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H228 |
Entzündbarer Feststoff. |
Entzündbare Feststoffe |
Kategorie 1 |
Achtung
Warnung |
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P210, P240,P241, P280, P370+P378 |
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| Sicherheit |
| P210 |
Von Hitze, hei?en Oberfl?chen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen. |
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Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
bright purple powder
Verwenden
suzuki reaction
l?uterung methode
Wash it repeatedly with Me2CO and MeOH and dry it in a vacuum. Alternatively dissolve it in CH2Cl2, concentrate it to half its volume, filter, add MeOH to precipitate it as purple microcrystals. Filter these off, wash several times with Me2CO and MeOH and dry them in a vacuum for several hours. [Scwab et al. J Am Chem Soc 118 100 1996, Miller et al. J Am Chem Soc 118 9606 1996, Furstner & Langermann J Am Chem Soc 119 9130 1997.] § A polymer supported version is available [Schwab et al. Angew Chem (Intl Edn) 34 2039 1995.].
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 315)Lieferanten
172222-30-9()Verwandte Suche:
- Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
- Phenylmethylenebis(tricyclohexlPhosPhine)ruthenium chloride
- GRUBB'S CATALYST 97%
- Bis-(tricyclohexylphosphine)-benzylideneruthenium
- Benzylidenebis(tricyclohexylphosphine)dichlororuthenium(IV)
- Bis(tricyclohexylphosphine)benzylidine ruthenium(lV) dichloride
- Grubbs (1st generation)
- Benzylidene-bis(tricyclohexylphosphine)dichlororutheniuM,Grubbs Catalyst 1st Generation
- Benzylidene-bis(tricyclohexylp
- Benzylidene-bis(tricyclohexylphosphine)dichlororut
- RutheniuM,dichloro(phenylMethylene)bis(tricyclohexylphosphine)-, (SP-5-31)-
- Grubbs Catalyst, 1st Generation 97%
- Benzylidenebis(tricyclohexylphosphoranyl)ruthenium(VI) chloride
- NAD+, Free Acid
- Grubbs catalyst 1st generation
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
- (Benzylidene)bis(tricyclohexylphosphine)ruthenium(4) Dichloride
- Grubbs Catalyst, 1st generation,Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine) benzylidine ruthenium(IV) chloride
- Bis(tricyclohexylphosphine)benzylidine ruthenium (IV) dichloride GRUBBS'S CATALYST
- Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine) benzylidine ruthenium(IV) chloride
- Grubb's catalyst,97%
- tricyclohexyl[dichloro(phenylMethylidene)(tricyclohexyl-$l^{5}-phosphanyl)ruthenio]-$l^{5}-phosphane
- Dichloro[(benzylidene)bis(tricyclohexylphosphine)]- rutheniuM(II)
- Benzylidene-bis(tricyclohexylphosphine)dichlororutheniuM, Grubbs Catalyst 1st Generation Grubbs
- BENZYLIDENE-BIS(TRIPHENYLPHOSPHINE)RUTHENIUM DICHLORIDE
- BIS(TRICYCLOHEXYLPHOSPHINE)BENZYLIDENERUTHENIUM(IV) DICHLORIDE
- RUTHENIUM,DICHLORO(PHENYLMETHYLENE)BIS (TRICYCLOHEXYLPHOSPHINE)
- ruthenium phosphine
- 1st generation catalyst
- idene-bis(tricycL
- ororuthenium
- phosphine)dichL
- Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, 97% [Grubbs Catalyst Gen. 1]
- Benzylidene-bis(tricyclohexylphosphine)dichlororutheniu
- Grubbs' 1st generation catalyst
- Grubbs Catalyst(TM) 1st Generation
- Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium ISO 9001：2015 REACH
- Benzylidene-bis(tricyclohexylphosphine)dichlororutheniumhine)dichlororuthenium
- Grubbs Catalyst,First Generation
- TIANFU CHEM Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
- Grubbs Gen.1
- Grubbs catalyst 2st generation Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
- Bis(tricyclohexylphosphine)benzylidine ruthenium (IV) chloride, Grubbs Catalyst 1st,
- Phenylmethylene bis (tricyclohexyl phosphate) ruthenium dichloride
- Grubbs Catalyst M102
- Palladium(Il)acetylacetonate(II)
- Validamine Impurity 2
- Grubbs Catalyst? M102
- Grubbs Catalyst? M102 ChemBeads
- Benzylidenebis(tricyclohexylphosphine)ruthenium(II)chloride
- Grubbs Catalyst Gen.1
- Grubbs 1st Grubbs Catalyst 1st Generation
- Grubbs Catalyst 1st Gen
- bis(tricyclohexylphosphine)benzylidine ruthenium dichloride
- Bis(tricyclohexylphosphine)benzylidine ruthenium (IV) dichloride
- Bis(tricyclohexylphosphine) benzylidine ruthenium(IV) chloride
- GRUBB'S CATALYST
- GRUBBS CATALYST, 1ST GENERATION
- Grubbs 1st Catalyst
