Bis(2-mercaptoethyl) sulfone
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- CAS-Nr.
- 145626-87-5
- Englisch Name:
- Bis(2-mercaptoethyl) sulfone
- Synonyma:
- Bis(2-thioethyl) sulphone;2,2'-Sulfonylbis-ethanethiol;2,2'-Sulphonyldiethane-1-thiol;Ethanethiol, 2,2'-sulfonylbis-;Bis(2-mercaptoethyl) sulphone, 2,2'-Sulphonyldiethanethiol
- CBNumber:
- CB11176170
- Summenformel:
- C4H10O2S3
- Molgewicht:
- 186.32
- MOL-Datei:
- 145626-87-5.mol
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Bis(2-mercaptoethyl) sulfone Eigenschaften
- Schmelzpunkt:
- 57-58°C
- Siedepunkt:
- 375.6±27.0 °C(Predicted)
- Dichte
- 1.296±0.06 g/cm3(Predicted)
- storage temp.
- -20°C Freezer, Under Inert Atmosphere
- L?slichkeit
- Chloroform (Slightly), Methanol (Slightly)
- Aggregatzustand
- solid
- pka
- pKa (aqueous soln at 25°): 7.9, 9.0
- Farbe
- Pale yellow
- Stabilit?t:
- Moisture Sensitive
- InChI
- 1S/C4H10O2S3/c5-9(6,3-1-7)4-2-8/h7-8H,1-4H2
- InChIKey
- YWXCBLUCVBSYNJ-UHFFFAOYSA-N
- SMILES
- [S](=O)(=O)(CCS)CCS
- CAS Datenbank
- 145626-87-5
Bis(2-mercaptoethyl) sulfone Chemische Eigenschaften,Einsatz,Produktion Methoden
Chemische Eigenschaften
White Crystalline Solid
Verwenden
Bis(2-mercaptoethyl) sulfone is a useful reagent for the reduction of disulfides in aquous solutions. It is a superior substitute for DTT.
l?uterung methode
BMS recrystallises from hexane as white fluffy crystals. Large amounts are best recrystallised from de-oxygenated H2O (charcoal). It is a good alternative reducing agent to dithiothreitol. Its IR (film) has 2995, 2657, 1306, 1248, 1124 and 729 cm-1 . The synthetic intermediate thioacetate has m 82-83o (white crystals from CCl4). The disulfide is purified by flash chromatography on SiO2 and elution with 50% EtOAc/hexane and recrystallised from hexane, and has m 137-139o. [Lamoureux & Whitesides J Org Chem 58 633 1993, Beilstein 1 IV 2455.]
Bis(2-mercaptoethyl) sulfone Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Bis(2-mercaptoethyl) sulfone Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 20)Lieferanten
- Bis(2-thioethyl) sulphone
- Bis(2-mercaptoethyl) sulphone, 2,2'-Sulphonyldiethanethiol
- 2,2'-Sulfonylbis-ethanethiol
- Ethanethiol, 2,2'-sulfonylbis-
- 2,2'-Sulphonyldiethane-1-thiol
- 145626-87-5
- Metal Isotopes
- Sulfur & Selenium Compounds
