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lithium allyl

lithium allyl Struktur
3052-45-7
CAS-Nr.
3052-45-7
Englisch Name:
lithium allyl
Synonyma:
allyllithium;lithium allyl;Lithium, 2-propenyl-
CBNumber:
CB14648049
Summenformel:
Molgewicht:
0
MOL-Datei:
Mol file

lithium allyl Eigenschaften

Siedepunkt:
59.6°C
L?slichkeit
sol in ethers with degrees of association 1.4-10; sparingly sol in alkanes
Aggregatzustand
colorless solid, pyrophoric in air

Sicherheit

lithium allyl Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

Lithium allyl is used as an allyling agent in substitution and addition reactions; used to attach allylic groups to other metals and nonmetals.

synthetische

Lithium allyl is prepared from allyl phenyl ether and Li in THF/ether is recommended for large scale, tinlithium exchange between allyltins and phenyllithium for pure samples.9 Halogen-metal exchange is  impractical due to fast Wurtz coupling. Allyllithium can also be made at -78 °C by the reaction of nButyllithium with allyl methyl (or phenyl) selenide,10 and by metallating propene with butyllithium.

lithium allyl Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


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  • lithium allyl
  • allyllithium
  • Lithium, 2-propenyl-
  • 3052-45-7
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