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Cyanoferrocene

Cyanoferrocene Struktur
1273-84-3
CAS-Nr.
1273-84-3
Englisch Name:
Cyanoferrocene
Synonyma:
Cyanoferrocene;Ferrocene, cyano-;Ferrocenylnitrile;Ferrocenyl cyanide;Cyclopentadienecarbonitrile, cyclopentadienyliron deriv.
CBNumber:
CB21457014
Summenformel:
C6H4N.C5H5.Fe
Molgewicht:
211.044
MOL-Datei:
1273-84-3.mol

Cyanoferrocene Eigenschaften

Schmelzpunkt:
107-108℃
storage temp. 
Storage temp. 2-8°C
Aussehen
Light yellow to yellow Solid
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Bildanzeige (GHS) Exclamation Mark (GHS07)
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung P264, P270, P301+P312, P330, P501
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung
Sicherheit
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

Cyanoferrocene Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Cyanoferrocene, [Fe(C5H5)(C6H4N)], forms sheets through hydrogen bonding. The N atom in the molecule accepts hydrogen bonds from C-H bonds in two other molecules, resulting in each molecule being hydrogen-bonded to four others. cyanoferrocene has occupied an important position since it can be converted to a structurally diverse set of ferrocenyl compounds that are attractive synthetic targets due to their chemical and biological properties.

synthetische

The synthesis of cyanoferrocene involved treating 3.1g (0.01 mol) of iodoferrocene and 3.6g (0.04 mol) of copper(I) cyanide with 20 ml of pyridine, using the same procedure used for preparing chloroferrocene. The resulting crude product was purified by chromatography on Florisil, yielding 1.75 g of cyanoferrocene with a yield of 83%. The melting point of cyanoferrocene was 106-107°C (lit. 107-108°C). A by-product of unidentified yellow crystals was also obtained, weighing 0.15g with a melting point of 157-158°C.

Einzelnachweise

The Reaction of Haloferrocenes with Copper(Ⅰ) Salts
DOI: 10.1246/bcsj.42.1976
Cyanoferrocene: a Two-Dimensional Network Generated by Short C-H...N Hydrogen Bonds
DOI: 10.1107/S0108270196006233
Efficient one-pot synthesis of cyanoferrocene from ferrocenecarboxaldehyde using NH2OH · HCl/KI/ZnO/CH3CN system
DOI: 10.1016/j.jorganchem.2007.02.002

Cyanoferrocene Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Cyanoferrocene Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 56)Lieferanten
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Shaanxi Dideu Medichem Co. Ltd
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Coresyn Pharmatech Co., Ltd.
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PT CHEM GROUP LIMITED
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GIHI CHEMICALS CO.,LIMITED
+86-571-86217390; +8618058761490
info@gihichemicals.com China 49938 58

1273-84-3()Verwandte Suche:


  • Cyclopentadienecarbonitrile, cyclopentadienyliron deriv.
  • Ferrocenyl cyanide
  • Ferrocenylnitrile
  • Ferrocene, cyano-
  • Cyanoferrocene
  • 1273-84-3
  • C11H9FeN
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