2-[(2,4-Dinitrophenyl)methyl]pyridin
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- CAS-Nr.
- 1151-97-9
- Bezeichnung:
- 2-[(2,4-Dinitrophenyl)methyl]pyridin
- Englisch Name:
- 2-(2,4-Dinitrobenzyl)pyridine
- Synonyma:
- AKOS 92219;TIMTEC-BB SBB003093;2-(2,4-DINITROBENZYL)PYRIDINE;2-(2,4-BISNITROBENZYL)PYRIDINE;2-(2,4-Dinitrobenzyl)pyridine >2-(2,4-Dinitrobenzyl)pyridine,99%;2-[(2,4-dinitrophenyl)methyl]-pyridin;2-[(2,4-dinitrophenyl)methyl]pyridine;Pyridine, 2-[(2,4-dinitrophenyl)Methyl]-;2-ACETYL-5-CHLORO-167-METHYLTHIANAPHTHENE
- CBNumber:
- CB2343620
- Summenformel:
- C12H9N3O4
- Molgewicht:
- 259.22
- MOL-Datei:
- 1151-97-9.mol
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2-[(2,4-Dinitrophenyl)methyl]pyridin Eigenschaften
- Schmelzpunkt:
- 92-94°C
- Siedepunkt:
- 402.47°C (rough estimate)
- Dichte
- 1.3450 (rough estimate)
- Brechungsindex
- 1.5700 (estimate)
- storage temp.
- Storage temp. 2-8°C
- Aggregatzustand
- powder to crystal
- pka
- 4.42±0.12(Predicted)
- Farbe
- White to Yellow to Green
- BRN
- 265115
- Stabilit?t:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- CAS Datenbank
- 1151-97-9(CAS DataBase Reference)
- EPA chemische Informationen
- Pyridine, 2-[(2,4-dinitrophenyl)methyl]- (1151-97-9)
2-[(2,4-Dinitrophenyl)methyl]pyridin Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
White to Yellow to Green powder to crystal.
Verwenden
2-(2,4-Dinitrobenzyl)pyridine can be used in organic synthesis and pharmaceutical intermediates.
synthetische
Synthesis of 2-(2,4-Dinitrobenzyl)pyridine
A solution of sulfuric acid (15 mL) is placed in an ice bath along with a magnetic stirrer.Benzylpyridine (2.4 mL) is added dropwise, maintaining a temperature below 10°C. This process is then repeated for fuming nitric acid (3.0 mL), once again maintaining the temperature. After addition mixture is allowed to stand at room temperature for 30minutes. Once completed reaction mixture is heated in an 80°C water bath for 20 minutes. Mixture is then poured into a conical flask containing crushed ice (50 cm3) which is stirred in an ice bath. Using a separating funnel aqueous ammonia is added (50 – 100 mL) until the pH rises to ~9 – 10 and filter using a Buchner funnel. Ethyl acetate (40mL) & sodium hydroxide (40mL) is added to the solid and stirred using a magnetic stirrer until dissolved.
Dry the organic layer using magnesium sulfate as the drying agent which is then followed by a rotary evaporator (40°C, vacuum). Product is then washed using cold methylated spirit and left to recrystalise.
2-[(2,4-Dinitrophenyl)methyl]pyridin Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
2-[(2,4-Dinitrophenyl)methyl]pyridin Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 83)Lieferanten
1151-97-9(2-[(2,4-Dinitrophenyl)methyl]pyridin)Verwandte Suche:
- 2-[(2,4-dinitrophenyl)methyl]-pyridin
- TIMTEC-BB SBB003093
- 2-(2,4-DINITROBENZYL)PYRIDINE
- 2-(2,4-BISNITROBENZYL)PYRIDINE
- 2-[(2,4-dinitrophenyl)methyl]pyridine
- 2-(2,4-Dinitrobenzyl)pyridine,99%
- AKOS 92219
- Pyridine, 2-[(2,4-dinitrophenyl)Methyl]-
- 2-(2,4-Dinitrobenzyl)pyridine >
- 2-ACETYL-5-CHLORO-167-METHYLTHIANAPHTHENE
- 1151-97-9
