(1R)-1,2,3,4,5,6-Hexahydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazocin-8-on Chemische Eigenschaften,Einsatz,Produktion Methoden
Beschreibung
This base was first prepared synthetically by Partheil and subsequently discovered
in the roots of Caulophyllurn thalictroides L. It is widespread among the Papilionaceae, being found in Baptisia australis, Genista tinctoria, Sophora
microphylla, S. tetraptera, Thermopsis lanceolata and T. rhombifolia (Watt.)
Richards. It is laevorotatory with [α]
20D - 221 ° (H20) and furnishes the following
crystalline salts and derivatives: hydrochloride, m.p. 2S0-SoC (dec.); hydriodide,
m.p. 246-7°C (dec.); perchlorate, m.p. 2S4°C (dec.); aurichloride, m.p.
206°C (dec.); picrate, m.p. 230°C; picrolonate, m.p. 224-SoC (dec.) and the
methiodide which occurs in two modifications, m.p. 248°C and 267-276°C.
Chemische Eigenschaften
Colourless Needles
Verwenden
N-Methylcytisine (cas# 486-86-2) is a compound useful in organic synthesis.
Allgemeine Beschreibung
N-Methylcytisine is a nicotinic alkaloid found in
Caulophyllum thalictroides, also known as blue cohosh.
Hazard
Extremely toxic; cardiotoxic; poisonous.
Einzelnachweise
Partheil., Arch. Pharm., 230,448 (1892)
Power, Salway., J. Chem. Soc., 103, 194 (1913)
(1R)-1,2,3,4,5,6-Hexahydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazocin-8-on Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
