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FMOC-LYS(BOC)(ME)-OH

FMOC-LYS(BOC)(ME)-OH Struktur
951695-85-5
CAS-Nr.
951695-85-5
Englisch Name:
FMOC-LYS(BOC)(ME)-OH
Synonyma:
FMOC-LYS(ME,BOC)-OH;N2-(((9H-fluoren-9-yl)methoxy)carbonyl)-N6-(tert-butoxycarbonyl)-N6-methyl-L-lysine;Fmoc-Lys(Me,Boc);FMOC-LYS(BOC)(ME)-OH;FMOC-L-LYS(BOC, ME)-OH;Boc-L-Lys(Fmoc)(Me)-OH;FMOC-LYSINE(BOC)(ME)-OH;Fmoc-Lys(Me,Boc)-OH,95%;Fmoc-Lys(Me,Boc)-OH, >=97%;FMOC-LYS(BOC)(ME)-OH USP/EP/BP
CBNumber:
CB3465262
Summenformel:
C27H34N2O6
Molgewicht:
482.57
MOL-Datei:
951695-85-5.mol

FMOC-LYS(BOC)(ME)-OH Eigenschaften

Schmelzpunkt:
85-87℃
Siedepunkt:
665.4±55.0 °C(Predicted)
Dichte
1.200
storage temp. 
-20°C
L?slichkeit
Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Aggregatzustand
Powder
pka
3.88±0.21(Predicted)
Farbe
White to off-white
Optische Rotation
-4°(C=0.01g/ml MEOH)
Major Application
peptide synthesis
InChIKey
JHMSFOFHTAYQLS-QHCPKHFHSA-N
SMILES
C(O)(=O)[C@H](CCCCN(C(OC(C)(C)C)=O)C)NC(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi
WGK Germany  WGK 2 water endangering
HS Code  2924 29 70
Speicherklasse 11 - Combustible Solids
Bildanzeige (GHS) Exclamation Mark (GHS07)
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung
Sicherheit
P261 Einatmen von Staub vermeiden.
P271 Nur im Freien oder in gut belüfteten R?umen verwenden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

FMOC-LYS(BOC)(ME)-OH Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Fmoc-lys (BOC) (ME)-OH is a kind of protected form of lysine. Lysine is double-protected by butyloxycarbonyl (BOC) and 9H-fluoren-9-ylmethoxycarbon (FMOC). It is a derivative for the introduction of monomethyl-lysine during Fmoc SPPS. Coupling can be carried out using any standard activation method. The Boc protecting group can be removed through the TFA-mediated cleavage reaction. As a kind of protected amino acid, it is an important intermediate in various fields such as peptide synthesis, asymmetric synthesis, medicinal chemistry as well as polymer chemistry.

Verwenden

  1. Heterochromatin protein 1 (HP1) depends on trimethylation of H3 Lys 9; aggregation of chromatines depends on Lys methylation
  2. Fmoc-Lys(Boc, Me)-OH is useful for preparing monomethylated histone fragments utilized in studying the regulatory roles of methylated histones. Fmoc-Lys(Boc,Me)-OH can be coupled using standard activating procedures. The Boc group on the side epsilon nitrogen atom is removed with TFA, usually at the same time as the peptide is cleaved from the resin.
  3. Fmoc-Lys(Boc, Me)-OH is a novel derivative for the introduction of monomethyl-lysine during Fmoc SPPS. Coupling can be carried out using any standard activation method. Removal of the Boc protecting group occurs during the course of the TFA-mediated cleavage reaction.

Allgemeine Beschreibung

Fmoc protected N-methylated lysine

Einzelnachweise

http://www.chempep.com/ChemPep_Products2_Fmoc-Amino-Acid_Fmoc-Lys_Boc_Me_-OH.htm
https://en.wikipedia.org/wiki/Peptide_synthesis
Tung, C. L., et al. "A fluorogenic probe for recognizing 5-hydroxylysine inspired by serine/threonine ligation. " Chemical Communications 50.40(2014):5298-300.

FMOC-LYS(BOC)(ME)-OH Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


FMOC-LYS(BOC)(ME)-OH Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 147)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Adachibio Inc.
+81-8027837258; +8108027837258
sales@adachibio.com Japan 938 58
career henan chemical co
+86-0371-86658258 +8613203830695
sales@coreychem.com China 29812 58
Biochempartner
0086-13720134139
candy@biochempartner.com CHINA 965 58
Alchem Pharmtech,Inc.
8485655694
sales@alchempharmtech.com United States 63687 58
GL Biochem (Shanghai) Ltd.
+86-021-61263370 +86-18901917034
CHINA 3904 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250
1026@dideu.com China 28760 58
Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 +8617705817739
info@dycnchem.com China 52704 58
Nextpeptide Inc
+86-0571-81612335 +8613336028439
sales@nextpeptide.com China 19908 58
Labnetwork lnc.
+86-27-50766799 +8618062016861
contact@labnetwork.com China 19987 58
Hunan Jibang Biological Technology Co., LTD
+8613776644403
sales02@kingboomtech.com China 1804 58

  • N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-N-EPSILON-TERT-BUTYLOXYCARBONYL-N-EPSILON-METHYL-L-LYSINE
  • N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-N-EPSILON-T-BUTYL-OXYCARBONYL-N-EPSILON-METHYL-L-LYSINE
  • N-ALPHA-(9-FLUORENYLMETHOXYCARBONYL)-N-EPSILON-T-BUTOXYCARBONYL-N-EPSILON-METHYL-L-LYSINE
  • N-ALPHA-FMOC-N-EPSILON,EPSILON-T-BOC-METHYL-L-LYSINE
  • N-ALPHA-FMOC-N-EPSILON-METHYL-N-EPSILON-T-BOC-L-LYSINE
  • FMOC-LYS(BOC)(ME)-OH
  • FMOC-LYSINE(BOC)(ME)-OH
  • FMOC-L-LYS(BOC, ME)-OH
  • N'-[(1,1-Dimethylethoxy)carbonyl]-N-[(9H-fluoren-9-ylmethoxy)carbonyl]-N'-methyl-L-lysine
  • (S)-1-(9H-fluoren-9-yl)-10,13,13-trimethyl-3,11-dioxo-2,12-dioxa-4,10-diazatetradecane-5-carboxylic acid
  • FMoc-N-epsilon-Methyl-N-epsilon-t-Boc-L-lysine
  • Fmoc-Lys(Me,Boc)-OH, >=97%
  • Nalpha-Fmoc-Nepsilon-methyl-Nepsilon-Boc-L-lysine
  • Fmoc-Lys(Me,Boc)-OH Novabiochem
  • (9H-Fluoren-9-yl)MethOxy]Carbonyl Lys(Boc, Me)-OH
  • Fmoc-Lys(Me,Boc)-OH N-Fmoc-N'-Boc-N'-Methyl-Lysine
  • N6-[(tert-Butoxy)carbonyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-N6-methyl-L-Lysine, 97%
  • L-Lysine, N6-[(1,1-dimethylethoxy)carbonyl]-N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-N6-methyl-
  • (2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-6-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]hexanoicaci
  • FMOC-LYS(BOC)(ME)-OH USP/EP/BP
  • Boc-L-Lys(Fmoc)(Me)-OH
  • N'-tert-butyloxycarbonyl-N-fluorenylmethoxycarbonyl-N'-methyl-L-lysine
  • (2S)-6-{[(tert-butoxy)carbonyl](methyl)amino}-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)hexanoic acid
  • (2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-6-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]hexanoic acid
  • Fmoc-Lys(Me,Boc)
  • N6-Boc-N2-Fmoc-N6-methyl-L-lysine
  • N2-(((9H-fluorene-9-yl)methoxy)oxo)-N6-(tertbutyloxyoxo)-N6-methyl-L-lysine
  • Fmoc-Lys(Me,Boc)-OH,95%
  • FMOC-LYS(ME,BOC)-OH
  • N2-(((9H-fluoren-9-yl)methoxy)carbonyl)-N6-(tert-butoxycarbonyl)-N6-methyl-L-lysine
  • N-Fmoc-Ne-methyl-Ne-Boc-L-lysine
  • 951695-85-5
  • amino acids
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