2,2'-Benzidinedisulfonic acid
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- CAS-Nr.
- 117-61-3
- Englisch Name:
- 2,2'-Benzidinedisulfonic acid
- Synonyma:
- BDSA;BENZIDINE 2,2 DISULFONIC ACID;70.0%(T);2,2'-Benzidinedisulf;Benzidine-2,2'-disuL;6,6'-bimetanilic acid;2,2'-disulfobenzidine;2,2’-disulfo-benzidin;BENZIDINEDISULPHONICACID;BENZIDINE 2-2'DISUFONIC ACID
- CBNumber:
- CB3732926
- Summenformel:
- C12H12N2O6S2
- Molgewicht:
- 344.36
- MOL-Datei:
- 117-61-3.mol
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2,2'-Benzidinedisulfonic acid Eigenschaften
- Schmelzpunkt:
- 175°C
- Siedepunkt:
- 638.25℃[at 101 325 Pa]
- Dichte
- 1.5417 (rough estimate)
- Dampfdruck
- 0Pa at 25℃
- Brechungsindex
- 1.6510 (estimate)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- -1.85±0.50(Predicted)
- Aggregatzustand
- Powder
- Farbe
- Dark purple
- Wasserl?slichkeit
- <0.1 g/100 mL at 20 ºC
- InChI
- InChI=1S/C12H12N2O6S2/c13-7-1-3-9(11(5-7)21(15,16)17)10-4-2-8(14)6-12(10)22(18,19)20/h1-6H,13-14H2,(H,15,16,17)(H,18,19,20)
- InChIKey
- MBJAPGAZEWPEFB-UHFFFAOYSA-N
- SMILES
- C1(C2=CC=C(N)C=C2S(O)(=O)=O)=CC=C(N)C=C1S(O)(=O)=O
- LogP
- 1.102 at 24℃
- CAS Datenbank
- 117-61-3(CAS DataBase Reference)
- EPA chemische Informationen
2,2'-Benzidinedisulfonic acid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R37/38:Reizt die Atmungsorgane und die Haut.
R36:Reizt die Augen.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
PURPLE CRYSTALLINE POWDER
Verwenden
4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff. Benzidine-2,2' -disulfonic acid is used in the production of yellow and red azo dyes.
Vorbereitung Methode
2,2'-Benzidinedisulfonic acid is made from the potassium or sodium salt of 3- nitrobenzenesulfonic acid by a gradual reduction using zinc dust and sodium hydroxide solution in a dilute aqueous solution. The product is subsequently rearranged using hydrochloric acid or dilute sulfuric acid. Electrochemical or catalytic reductions are also possible.
Allgemeine Beschreibung
Leaflets or prisms or light purple powder.
Air & Water Reaktionen
Insoluble in water.
Brandgefahr
Flash point data for 2,2'-Benzidinedisulfonic acid are not available; however, 2,2'-Benzidinedisulfonic acid is probably combustible.
Sicherheitsprofil
A severe eye irritant. When heated to decomposition it emitsvery toxic fumes of SOx and NOx.
2,2'-Benzidinedisulfonic acid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
REACTIVE ORANGE 84
Dinatrium-4,4'-bis(2-hydroxynaphthalin-1-ylazo)biphenyl-2,6'-disulfonat
4,4'-Bis[(2-methyl-1H-indol-3-yl)azo]-1,1'-biphenyl-2,2'-disulfonic acid disodium salt
trisodium 4-[[7-[(2,4-diaminophenyl)azo]-1-hydroxy-3-sulphonato-2-naphthyl]azo]-4'-[(4-hydroxyphenyl)azo][1,1'-biphenyl]-2,2'-disulphonate
Dinatrium-4-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]-4'-[(2-hydroxy-1-naphthyl)azo][1,1'-biphenyl]-2,2'-disulfonat
Tetranatrium-5,5'-[(2,2'-disulfonato[1,1'-biphenyl]-4,4'-diyl)bis(azo)]disalicylat
4,4'-Bis[[2-hydroxy-3-[(phenylamino)carbonyl]-1-naphthyl]azo][1,1'-biphenyl]-2,2'-disulfondinatriumsure
Acid Red 444
Dinatrium-4,4'-bis(5-hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-ylazo)-1,1'-biphenyl-2,6'-disulfonat
2,2'-Benzidinedisulfonic acid Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 280)Lieferanten
117-61-3()Verwandte Suche:
Schwefligesure
Benzidin
4,4'-Diamino-5,5'-dimethylbiphenyl-2,2'-disulfonsure
Dinatrium-4,4'-bis(5-hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-ylazo)-1,1'-biphenyl-2,6'-disulfonat
Dinatrium-4,4'-bis(2-hydroxynaphthalin-1-ylazo)biphenyl-2,6'-disulfonat
Tetranatrium-5,5'-[(2,2'-disulfonato[1,1'-biphenyl]-4,4'-diyl)bis(azo)]disalicylat
Dinatrium-5,5'-dimethyl-4,4'-bis[[2-oxo-1-[(phenylamino)carbonyl]propyl]azo][1,1'-biphenyl]-2,2'-disulfonat
Dinatrium-4-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]-4'-[(2-hydroxy-1-naphthyl)azo][1,1'-biphenyl]-2,2'-disulfonat
- 4,4’-diaminodiphenyl-2,2’-disulfonicacid
- kyselinabenzidin-2,2’-disulfonova
- 2,2'-disulfo-4,4'diaminobibenzene
- 2,2'-BENZIDINEDISULFONIC ACID (CONTAINS 30% WATER AT MAXIMUM) 70+%
- 2,2’-BENZIDINE-DISULPHONIC ACID， HPLC 96+％
- 6,6'-bimetanilic acid
- 2,2'-Disulfo-4,4'-diaminobiphenyl
- 2,2'-disulfobenzidine
- 2,2'-DISULFONIC ACID BENZIDINE
- 1’-biphenyl)-2,2’-disulfonicacid,4,4’-diamino-(
- 1’-biphenyl]-2,2’-disulfonicacid,4,4’-diamino-[
- 1’-Biphenyl]-2,2’-disulfonicacid,4,4’-diamino-[1
- benzidine-2,2'-disulphonic acid
- BENZIDINEDISULPHONICACID
- 2,2''-BENZIDINEDISULFONIC ACID: 70% (CONTAINS MAX. 30% WATER)
- 4,4''-DIAMINEDIPHENY-2,2''-DISULFONICACID
- 4,4'-Diamino-2,2'-biphenyldisulfonic acid, tech. 70+%
- 2,2'-Benzidinedisulfonic Acid (contains 30% Water at maximum)
- 4,4'-Diamino-2,2'-biphenyldisulfonic acid, 70+%
- [1,1'-Biphenyl]-2,2'-disulfonic acid, 4,4'-diamino-
- 2,2'-Biphenyldisulfonic acid, 4,4'-diamino
- 4,4'-Diamino-1,1'-biphenyl-2,2'-bissulfonic acid
- 4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate, cont. up to 30% water
- 4,4'-Diamino-2,2'-biphenyldisulfonic acid,85%,tech.
- (contains 30% Water at MaxiMuM)
- 2,2'-Benzidinedisulfonic Acid
- 4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate
- 2,2'-Benzidinedisulf
- 4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate,may contain up to 30% water
- 4,4'-Diamino-(1,1'-biphenyl)-2,2'-disulfonic acid
- 4,4'-Diaminobiphenyl-2,2'-disulfonic acid
- 2,2’-diamino-4’-biphenyldisulfonicacid
- 2,2’-disulfo-benzidin
- 4,4’-diamino-2’-biphenyldisulfonicacid
- 4,4'-Diamino-[1,1'-biphenyl]-2,2'-disulfonic acid(contains 30% Water at maximum)
- 2,2'-Benzidinedisulfonic acid, 70%, water ≤30%
- 5-amino-2-(4-amino-2-sulfophenyl)benzenesulfonic acid
- BENZIDINE 2-2'DISUFONIC ACID
- 2,2'-Benzidinedisulfonic Acid (contains 30% Water at maximum)>
- 70.0%(T)
- Benzidine-2,2'-disuL
- 5-amino-2-(4-amino-2-sulfophenyl)benzenesulfonicaci
- 4,4’-Diamino-2,2’-biphenyldisulfonic Acid (contains 30% Water
at maximum)
- Benzidine-2,2'-disulfonic acid/BDSA
- TIANFUCHEM--High purity 117-61-3 2,2'-Benzidinedisulfonic acid
- 2,2'-Benzidinedisulfonic Acid (contains 20% Water at maximum)
- BENZIDINE 2,2 DISULFONIC ACID
- 2,2'-Benzidinedisulfonic acid
- Benzidine-2,2'-disulfonic acid
- 4,4'-Diamino-2,2'-biphenyldisulfonic acid
- 4,4'-diamino[1,1'-biphenyl]-2,2'-disulfonic acid
- 2,2'-benzidinedisulfonic acid
- BDSA
- 117-61-3
- H2NC6H3SO3H2
- C12H12N2O6S2
- Intermediates of Dyes and Pigments
- Biphenyl & Diphenyl ether
