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stemmadenine

stemmadenine Struktur
10012-73-4
CAS-Nr.
10012-73-4
Englisch Name:
stemmadenine
Synonyma:
stemmadenine;15-epi-Stemmadenine;(19E)-2,7,19,20-Tetradehydro-17-hydroxy-3,7-secocuran-16-carboxylic acid methyl ester;(15β,19E)-2,7,19,20-Tetradehydro-17-hydroxy-3,7-secocuran-16-carboxylic acid methyl ester;1H-3,6-Ethanoazonino[5,4-b]indole-7-carboxylic acid, 5-ethylidene-2,4,5,6,7,8-hexahydro-7-(hydroxymethyl)-, methyl ester, (3S,5E,6S,7S)-
CBNumber:
CB41388808
Summenformel:
C21H26N2O3
Molgewicht:
354.44
MOL-Datei:
10012-73-4.mol

stemmadenine Eigenschaften

Schmelzpunkt:
189-193°C
Siedepunkt:
518.5±50.0 °C(Predicted)
Dichte
1.27±0.1 g/cm3(Predicted)
pka
14.81±0.10(Predicted)

Sicherheit

stemmadenine Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

First isolated from various species of Stemmadenia, this alkaloid has subsequently been found in DipZorrhynchus rondyZocarpon subsp. mossambiensis Benth. and MeZodinus australis. The following specific rotations have been reported; [α]19D + 310° (c 0.527, pyridine), [α]20D~O + 329° (pyridine) and [α]25D~S + 324° (pyridine). The alkaloid gives an ultraviolet spectrum exhibiting absorption maxima at 227, 284 and 292 m/J. with shoulders at 275 and 305 m/J.. One nitrogen atom is tertiary, the other being part of the indole ring. The solution in concentrated HN03 is a bright yellow.

Einzelnachweise

Watts, Collera, Sandoval., Tetrahedron, 2, 173 (1958)
Stauffacher., HeZv. Chim. Acta, 44, 2006 (1961)
Sandoval et aZ., Tetrahedron Lett., 409 (1962)
Schumann, Schmid., HeZv. Chim. Acta., 46, 1996 (1963)
Linde., ibid, 48,1822 (1965)

stemmadenine Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


stemmadenine Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 6)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
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RENI Pharmaceutical Technology Co., Ltd 028-87865381 18108190480
3961643053@qq.com China 4321 58
Shanghai YanyiBao Pharmaceutical Technology Co., Ltd. 13661744693
wangyue@yybyy.com China 1045 58

10012-73-4()Verwandte Suche:


  • stemmadenine
  • (15β,19E)-2,7,19,20-Tetradehydro-17-hydroxy-3,7-secocuran-16-carboxylic acid methyl ester
  • (19E)-2,7,19,20-Tetradehydro-17-hydroxy-3,7-secocuran-16-carboxylic acid methyl ester
  • 15-epi-Stemmadenine
  • 1H-3,6-Ethanoazonino[5,4-b]indole-7-carboxylic acid, 5-ethylidene-2,4,5,6,7,8-hexahydro-7-(hydroxymethyl)-, methyl ester, (3S,5E,6S,7S)-
  • 10012-73-4
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