Di-μ-chlorobis[(1,2,5,6-?)cycloocta-1,5-dien]diiridium
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- CAS-Nr.
- 12112-67-3
- Bezeichnung:
- Di-μ-chlorobis[(1,2,5,6-?)cycloocta-1,5-dien]diiridium
- Englisch Name:
- Chloro(1,5-cyclooctadiene)iridium(I) dimer
- Synonyma:
- [Ir(COD)Cl]2;BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE;[Ir(1,5-cod)Cl]2;Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium;IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER;Bis(1,5-cyclooctadiene)diiridium(I) Dichloride ([Ir(cod)Cl]2);HS157;Chloro(1;683094-500MG;IRIDIUM COD CHLORIDE
- CBNumber:
- CB4212508
- Summenformel:
- C16H24Cl2Ir2
- Molgewicht:
- 671.7
- MOL-Datei:
- 12112-67-3.mol
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Di-μ-chlorobis[(1,2,5,6-?)cycloocta-1,5-dien]diiridium Eigenschaften
- Schmelzpunkt:
- 205 °C (dec.)(lit.)
- storage temp.
- Keep in dark place,Inert atmosphere,2-8°C
- L?slichkeit
- Chloroform (Slightly), Methanol (Slightly)
- Aggregatzustand
- Powder
- Farbe
- red to orange
- Wasserl?slichkeit
- insoluble
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- InChI
- InChI=1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
- InChIKey
- XHOSESNLNGITPM-XRGHXPOKSA-L
- SMILES
- C1C=CCCC=CC1.C1C=CCCC=CC1.Cl[Ir].Cl[Ir] |c:1,5,9,13|
Di-μ-chlorobis[(1,2,5,6-?)cycloocta-1,5-dien]diiridium Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Chemische Eigenschaften
red-orange solid
Verwenden
Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.
Synthese
A solution of 6 mL of 1,5-cyclooctadiene in 35 mL of ethanol and 20 mL of water is added to 2.0 g of IrCl3.3H2O in a round-bottomed flask. The mixture is refluxed under nitrogen for 24 h when an orange-red product precipitates from the solution. The mixture is cooled to rt, and Di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) (Chloro(1,5-cyclooctadiene)iridium(I) dimer) is collected by filtration, washed with cold methanol, and dried in vacuo at 25 °C for 8 h.
Di-μ-chlorobis[(1,2,5,6-?)cycloocta-1,5-dien]diiridium Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Di-μ-chlorobis[(1,2,5,6-?)cycloocta-1,5-dien]diiridium Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 372)Lieferanten
12112-67-3(Di-μ-chlorobis[(1,2,5,6-?)cycloocta-1,5-dien]diiridium)Verwandte Suche:
DILINOLEIC ACID
Iridium
Iridium(III) chloride hydrate
Di-μ-chlor-bis(?-1,5-cyclooctadien)dirhodium(I)
Cycloocta-1,5-dien
POLYALUMINUM CHLORIDE
POLYETHYLENE, CHLORINATED
Cycloocta-1,3-dien
Cobaltchlorid
Chlordifluormethan
(Z,Z)-Cycloocta-1,5-dien
Di-μ-chlorobis[(1,2,5,6-?)cycloocta-1,5-dien]diiridium
ALKYLKETENE DIMER
Chlorinated polyethylene water-proof rolled materials
- DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)IRIDIUM (I)]
- DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM
- CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER
- CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER
- IRIDIUM I CYCLOOCTADIENE CHLORIDE
- IRIDIUM CHLORO-1,5-CYCLOOCTADIENE
- IRIDIUM COD CHLORIDE
- 1,5-CYCLOOCTADIENE-IRIDIUM(I) CHLORIDE DIMER
- chloro(1,5-cyclooctadiene)iridium(i)
- BIS(1,5-CYCLOOCTADIEN)DIIRIDIUM(I)-DICHL ORIDE
- BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DIC&
- Chloro(1,5-cyclooctadiene)iridium(I), dimer,99.9%
- Chloro(1,5-cyclooctadiene)iridium(I)dimere
- di-mu-chlorobis[(1,2,5,6-eta)cycloocta-1,5-diene]diiridium
- Chloro-1,5-cyclooctadieneiridium(I)dimer,99%
- CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER (57%IR)
- Chloro-(1,5-cyclooctadiene)-iridium dimer
- Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
- Chloro(1,5-cyclooctadiene)iridium(I)dimer dec. 190
- Chloro(1,5-cyclooctadiene)iridium(I) dimer ,98%
- "Di-chloro bis(cycloocta-1,5-dienyl)iridium(I)"
- Bis(1,5-cyclooctadiene)diiridium(I) dichloride,1,5-Cyclooctadiene-iridium(I) chloride dimer, Chloro(1,5-cyclooctadiene)iridium(I) dimer, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Iridiu
- Chloro(1,5-cyclooctadiene)iridiuM(I) diMer 250MG
- IridiuM, di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]di-
- Chloro(1,5-cyclooctadiene)iridiuM(I) diMer,98% [Ir(COD)Cl]2
- IRIDIUM(I) CYCLOOCTADIENE CHLORIDE, diMer
- Chloro(1,5-cyclooctadiene)iridium(Ⅰ) dimer
- Chloro(1,5-cyclooctadiene)iridiuM(I) diMer,[Ir(COD)Cl]2
- Bis(1,5-cyclooctadiene)diiridiuM(I) dichloride 97%
- 1,5-octadiene iridiuM chloride diMer
- Dichloro(1,5-cyclooctadien)iridium(I) dimer
- Chloroiridium - cycloocta-1,5-diene (1:1)
- 5-cyclooctadiene)iridium(I) dimer
- Chloro(1
- Chloro(1,5-cyclooctadiene)iridium(I) Dimer >
- ooctadiene)diiridium(I) dichL
- Chloro(1,5-cyclooctadiene)iridium(I) dimer ISO 9001：2015 REACH
- TIANFU CHEM Chloro(1,5-cyclooctadiene)iridium(I) dimer
- IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER
- Bis(1,5-cyclooctadiene)diiridium(I) Dichloride ([Ir(cod)Cl]2)
- Di( μ -chloro)bis(1,5-cyclooctadiene)diiridium(I)
- Chloro-1,5-cyclooctadiene iridium(I) dimmer
- Chloroiridium-cycloocta-1,5-diene
- CHLORO(1,5-CYCLOOTADIENE)IRIDIUM(I) DIMER
- Chloro(1,5-cyclooctadiene
- Palladium pivalate(l)
- HS157
- Dichloro(1,5-cyclooctadiene)iridium(III)dimer
- Bis(1,5-cyclooctadiene)diiridium(I) dichloride，98% min Ir:56.5% min
- 683094-500MG
- [Ir(COD)Cl]2 / Chloro(1,5-cyclooctadiene)iridium(I) dimer
- [Ir(1,5-cod)Cl]2
- [Ir(COD)Cl]2
- BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE
- Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium
- 12112-67-3
- 12112-67-2
- C16H24Ir2Cl2
