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2,8-Bis(diphenylphosphoryl)dibenzo[b,d]thiophene

2,8-Bis(diphenylphosphoryl)dibenzo[b,d]thiophene Struktur
1019842-99-9
CAS-Nr.
1019842-99-9
Englisch Name:
2,8-Bis(diphenylphosphoryl)dibenzo[b,d]thiophene
Synonyma:
PPT;LT-N4006;PPT, PO15;PPT sublimed;4'-PHOSPHOPANTETHEINE;2,8-Bis(diphenylphosphoryl)dibenzothiophene;2,8-Bis(diphenylphosphinyl)dibenzothiophene;2,8-bis(diphenylphosphoryl)dibenzo[b,d]thiophene;2,8-Bis(diphenylphosphoryl)dibenzo[b,d ]t hiophen;PPT , 2,8-bis(diphenylphosphoryl)dibenzo[b,d]thiophene
CBNumber:
CB4291156
Summenformel:
C36H26O2P2S
Molgewicht:
584.6
MOL-Datei:
Mol file

2,8-Bis(diphenylphosphoryl)dibenzo[b,d]thiophene Eigenschaften

Siedepunkt:
830.1±60.0 °C(Predicted)
Dichte
1.34±0.1 g/cm3(Predicted)
storage temp. 
Store at room temperature
Aggregatzustand
solid
Farbe
white
InChI
1S/C36H26O2P2S/c37-39(27-13-5-1-6-14-27,28-15-7-2-8-16-28)31-21-23-35-33(25-31)34-26-32(22-24-36(34)41-35)40(38,29-17-9-3-10-18-29)30-19-11-4-12-20-30/h1-26H
InChIKey
FLOCBCIFBBVRCJ-UHFFFAOYSA-N
SMILES
C12=CC=C(P(OC3=CC=CC=C3)(OC3=CC=CC=C3)=O)C=C1C1=CC(P(OC3=CC=CC=C3)(OC3=CC=CC=C3)=O)=CC=C1S2
Schmelzpunkt:
TGA: >320 °C(0.5% weight loss)
Absorption
λmax312, 328 nm in DCM

Sicherheit

WGK Germany  WGK 3
Speicherklasse 11 - Combustible Solids

2,8-Bis(diphenylphosphoryl)dibenzo[b,d]thiophene Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

PPT is an ambipolarphosphorescent host materials with an electron-rich dibenzothiophene core and two electron-deficientdiphenyl-phosphoryl side arms. For this reason,PPT is a good electron-transport material with higher electron mobility rate, offering better electron injection.

Verwenden

2,8-Bis(diphenylphosphoryl)dibenzo[b,d]thiophene (PPT) can be used as an electro-transport material to enhance the efficiency and lifetime of inverted organic light-emitting diodes (iOLEDs), but its performance is lower than 2,8-bis(diphenylphosphoryl)dibenzo[b,d]thiophene sulfone (PPT-S)[1]. In addition, PPT is also employed in the preparation of organic amorphous films. Research indicates that pure PPT films exhibit negative spontaneous orientational polarisation (SOP), yet this polarity can transition to positive SOP with increasing concentrations of non-polar molecules[2].
[1] SHIZUKA KAWAMURA. Effects of Energy-Level Alignment on Characteristics of Inverted Organic Light-Emitting Diodes[J]. ACS Applied Materials & Interfaces, 2019, 11 24: 21749-21755. DOI:10.1021/acsami.9b03895.
[2] YUUHI UEDA . A polar transition of spontaneous orientation polarization in organic amorphous thin films[J]. Chemical Physics Letters, 2023, 833: Article 140915. DOI:10.1016/j.cplett.2023.140915.

2,8-Bis(diphenylphosphoryl)dibenzo[b,d]thiophene Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


2,8-Bis(diphenylphosphoryl)dibenzo[b,d]thiophene Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • PPT
  • 4'-PHOSPHOPANTETHEINE
  • 2,8-bis(diphenylphosphoryl)dibenzo[b,d]thiophene
  • PPT , 2,8-bis(diphenylphosphoryl)dibenzo[b,d]thiophene
  • 1,1'-(2,8-Dibenzothiophenediyl)bis[1,1-diphenylphosphine oxide
  • 2,8-Bis(diphenylphosphoryl)dibenzothiophene
  • dibenzo[b,d]thiophene-2,8-diylbis(diphenylphosphine oxide)
  • 2,8-Bis(diphenylphosphoryl)dibenzo[b,d ]t hiophen
  • Phosphine oxide, 1,1'-(2,8-dibenzothiophenediyl)bis[1,1-diphenyl-
  • OC1039, Dibenzo[b,d]thiophene-2,8-diylbis(diphenylphosphine oxide)
  • LT-N4006
  • PPT sublimed
  • PPT, PO15
  • 2,8-Bis(diphenylphosphinyl)dibenzothiophene
  • 1019842-99-9
  • C36H26O2P2S
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