TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)
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- CAS-Nr.
- 76262-87-8
- Englisch Name:
- TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)
- Synonyma:
- Titanocene ditriflate;TITANOCENE BIS(TRIFLUOROMETHANESULFONATE);Bis(cyclopentadienyl)di(triflato)titanium;TITANOCENE BIS(TRIFLUOROMETHANESULPHONATE);Bis(cyclopentadienyl)bis(trifluoromethanesulfonato)titanium;Bis(trifluoromethanesulfonate)dicyclopentadienyltitanium(IV);BIS(CYCLOPENTADIENYL)TITANIUM BIS(TRIFLUOROMETHANESULFONATE);di(cyclopentadienyl)titanium(iv) bis(trifluoromethanesulfonate);BIS(CYCLOPENTADIENYL)TITANIUM(IV) BIS(TRIFLUOROMETHANESULFONATE);Titanocene bis(trifluoromethanesulfonate), Di(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)
- CBNumber:
- CB1163434
- Summenformel:
- C12F6O6S2Ti
- Molgewicht:
- 466.1
- MOL-Datei:
- 76262-87-8.mol
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TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Eigenschaften
- L?slichkeit
- sol CH2Cl2, MeNO2; insol benzene, hexane.
- Aggregatzustand
- powder to crystal
- Farbe
- Orange to Amber to Dark red
- InChI
- 1S/2C5H5.2CHF3O3S.Ti/c2*1-2-4-5-3-1;2*2-1(3,4)8(5,6)7;/h2*1-5H;2*(H,5,6,7);/q;;;;+2/p-2
- InChIKey
- ARUXRBUQJOYABI-UHFFFAOYSA-L
- SMILES
- [Ti++].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
- CAS Datenbank
- 76262-87-8
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Verwenden
Catalyst for:
- Transesterification
- Stereoselective carbonyl-ene cyclization reactions
- Sakurai reactions
- Mukaiyama cross-aldol reactions
Reactant for synthesis of heterobimetallic bridging dinitrogen complexes
synthetische
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) is prepared by treatment of a 0.06 M THF solution of
Dichlorobis(cyclopentadienyl)titanium with 5.5 equiv of a 0.19 M THF solution of Silver(I)
Trifluoromethanesulfonate. After stirring for 15 min the reaction mixture is filtered, the red filtrate is
layered with hexane, and the resulting red crystals are collected. Recrystallization from CH2Cl2/pentane or
THF/hexane affords Cp2Ti(OSO2CF3)2 (25-30%) as red needles.
Application
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) is used as a catalyst for Diels-Alder reaction, Mukaiyama crossed-aldol reaction, and Sakurai reaction.
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 49)Lieferanten
76262-87-8()Verwandte Suche:
- TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)
- BIS(CYCLOPENTADIENYL)TITANIUM(IV) BIS(TRIFLUOROMETHANESULFONATE)
- BIS(CYCLOPENTADIENYL)TITANIUM BIS(TRIFLUOROMETHANESULFONATE)
- TITANOCENE BIS(TRIFLUOROMETHANESULPHONATE)
- di(cyclopentadienyl)titanium(iv) bis(trifluoromethanesulfonate)
- Bis(cyclopentadienyl)bis(trifluoromethanesulfonato)titanium
- Bis(cyclopentadienyl)di(triflato)titanium
- Bis(trifluoromethanesulfonate)dicyclopentadienyltitanium(IV)
- Titanocene ditriflate
- Titanocene bis(trifluoromethanesulfonate), Di(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)
- 76262-87-8
- C12H10F6O6S2Ti
- Titanium
- Catalysis and Inorganic Chemistry
- Titanocene, etc.
- Metallocenes
- Classes of Metal Compounds
- Transition Metal Compounds
- Ti (Titanium) Compounds
- Classes of Metal Compounds
- Metallocenes
- Ti (Titanium) Compounds
- Titanocene, etc.
- Transition Metal Compounds
