nuttaline Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

A major constituent of Lupinus nuttallii, this alkaloid is dextrorotatory with [α] ²⁴ _D + 25.3 ± 0.9° (c 2.0, EtOH). It has been characterized as the perchlorate, m.p. l70-2°C. Prolonged treatment with NaBH4 yields (-)-4/3-hydroxysparteine, yielding a perchlorate, m.p. 248-2500 C. Oppenauer oxidation of the alkaloid gives 2:4-dioxosparteine. The structure has been established by treatment of the base with P20 S to give (+)-2-oxo-3:4-didehydrosparteine which, on catalytic hydrogenation is converted into deoxynuttalline, identified as (+ )-lupanine by comparison with an authentic specimen.

Einzelnachweise

Goldberg, Balthis., 1. Chern. Soc., D, 660 (1969)

nuttaline Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

nuttaline Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Firmenname	Telefon	E-Mail	Land	Produktkatalog	Edge Rate

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• nuttaline
• (2S,7α,7aβ,14α,14aα)-Dodecahydro-2-hydroxy-7,14-methano-4H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-4-one
• 7,14-Methano-2H,11H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-11-one, dodecahydro-9-hydroxy-, (7S,7aR,9S,14S,14aS)-
• Nuttalline
• 23360-87-4