1-Bromo-4-(pentafluorosulfanyl)benzene
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- CAS-Nr.
- 774-93-6
- Englisch Name:
- 1-Bromo-4-(pentafluorosulfanyl)benzene
- Synonyma:
- (4-Bromophenyl)pentafluoro-l6-sulfane;4-BROMOPHENYLSULFUR PENTAFLUORIDE;4-BROMOPHENYL-PENTAFLUOROSULFUR;4-Pentafluorosulfur bromobenzene;p-Bromophenylsulfur Pentafluoride;4-BROMOPHENYLSULPHUR PENTAFLUORIDE;1-BROMO-4-(PENTAFLUOROTHIO)BENZENE;4-Bromophenylsulfur Pentafluoride >1-BROMO-4-(PENTAFLUOROSULFANYL)BENZENE;4-BroMophenylsulfur pentafluoride, 95+%
- CBNumber:
- CB5263002
- Summenformel:
- C6H4BrF5S
- Molgewicht:
- 283.06
- MOL-Datei:
- 774-93-6.mol
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1-Bromo-4-(pentafluorosulfanyl)benzene Eigenschaften
- Siedepunkt:
- 77.2 °C(Press: 10 Torr)
- Brechungsindex
- 1.4790-1.4830
- Flammpunkt:
- 84°C(lit.)
- storage temp.
- 0-10°C
- Aggregatzustand
- liquid
- Farbe
- Clear, colourless
- InChI
- InChI=1S/C6H4BrF5S/c7-5-1-3-6(4-2-5)13(8,9,10,11)12/h1-4H
- InChIKey
- RECCABBXFXGELM-UHFFFAOYSA-N
- SMILES
- S(F)(F)(F)(F)(F)C1=CC=C(Br)C=C1
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Bildanzeige (GHS) |
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H227 |
Combustible liquid |
Flammable liquids |
Category 4 |
Warnung |
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P210, P280, P370+P378, P403+P235,P501 |
| H302 |
Gesundheitssch?dlich bei Verschlucken. |
Akute Toxizit?t oral |
Kategorie 4 |
Warnung |
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P264, P270, P301+P312, P330, P501 |
| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
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P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
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P264, P280, P305+P351+P338,P337+P313P |
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| Sicherheit |
| P210 |
Von Hitze, hei?en Oberfl?chen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P270 |
Bei Gebrauch nicht essen, trinken oder rauchen. |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P403+P235 |
An einem gut belüfteten Ort aufbewahren. Kühl halten. |
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1-Bromo-4-(pentafluorosulfanyl)benzene Chemische Eigenschaften,Einsatz,Produktion Methoden
Synthese
5.0 g of 4-pentafluorosulfanylaniline was dissolved in 20 ml of acetic acid, and, at 0 ℃, a saturated aqueous HBr solution was added. Then, at 0 ℃, a solution of 1.9 of NaNO2 in 5 ml of water was slowly added dropwise over the course of 5 minutes. The reaction mixture was stirred at 0 C. for 10 minutes and then added in portions to a suspension of 6.5 g of CuBr in 20 ml of a half-saturated aqueous HBr solution at 0 ℃. Nitrogen is liberated during this. The mixture was stirred at 0 ℃. for 30 minutes and then at RT for 1 h. It was subsequently extracted 3 times with 100 ml of HEP each time, and then the HEP was washed twice with 50 ml of a saturated aqueous Na2CO3 solution each time. The residue, after drying over MgSO4 and removal of the solvent in vacuo, was chromatographed on silica gel with HEP. 1.8 g of a colorless oil 1-Bromo-4-(pentafluorosulfanyl)benzene were obtained.
1-Bromo-4-(pentafluorosulfanyl)benzene Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
1-Bromo-4-(pentafluorosulfanyl)benzene Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 73)Lieferanten
774-93-6()Verwandte Suche:
- 4-BROMOPHENYL-PENTAFLUOROSULFUR
- 4-BROMOPHENYLSULPHUR PENTAFLUORIDE
- 1-BROMO-4-(PENTAFLUOROSULFANYL)BENZENE
- 1-BROMO-4-(PENTAFLUOROTHIO)BENZENE
- 4-Pentafluorosulfur bromobenzene
- 1-Bromo-4-(pentafluorothio)benzene, 1-Bromo-4-(pentafluorosulphanyl)benzene
- 4-BroMophenylsulfur pentafluoride, 95+%
- Sulfur,(4-broMophenyl)pentafluoro-, (OC-6-21)- (9CI)
- Sulfur, (4-bromophenyl)pentafluoro-, (OC-6-21)-
- 4-Bromophenylsulfur Pentafluoride >
- p-Bromophenylsulfur Pentafluoride
- (OC-6-21)-(4-Bromophenyl)pentafluorosulfur
- (4-bromophenyl)-pentafluoro-lambda6-sulfane
- (4-Bromophenyl)pentafluoro-l6-sulfane
- 4-BROMOPHENYLSULFUR PENTAFLUORIDE
- 774-93-6
- C6H4F5BrS
- Halides
- Phenyls & Phenyl-Het
- Phenyls & Phenyl-Het
