LITHIUM ARSENIDE Chemische Eigenschaften,Einsatz,Produktion Methoden
synthetische
To obtain Li3As, a suspension of freshly powdered As in anhydrous liquid NH3 is prepared. A solution of Li in dried liquid ammonia is added, in small portions, to the suspension. The reaction begins on shaking. Its termination is indicated by the appearance of a blue color in the supernatant fluid, due to a slight excess of Li. The NH3 is boiled out, with the last traces removed by vacuum. The products are either the brown Li3As powder (very air sensitive; must be stored under pure N2 or Ar) or blue-gray β-Li3Sb powder. The particle size of the latter can be increased by heating at 650℃. Another modification, α-Li3Sb, is obtained by quenching of the melt (m.p. between 1150 and 1300℃) under Ar in a thick-walled iron crucible with welded-on lid.
LITHIUM ARSENIDE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
