d-Camphersure
|
|
|
- CAS-Nr.
- 124-83-4
- Bezeichnung:
- d-Camphersure
- Englisch Name:
- D-(+)-Camphoric acid
- Synonyma:
- (+)-CAMPHORIC ACID;(1R,3S)-CAMPHORIC ACID;(1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid;(1R,3S)-(+)-CAMPHORIC ACID;D-(+)-Camphoric;(1R)-cis-Camphoric acid;(1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-;D-caMphor acid;D-(+)-Camphoricaci
- CBNumber:
- CB5296789
- Summenformel:
- C10H16O4
- Molgewicht:
- 200.23
- MOL-Datei:
- 124-83-4.mol
|
d-Camphersure Eigenschaften
- Schmelzpunkt:
- 186-189 °C
- alpha
- 46.5 º (c=10, C2H5OH)
- Siedepunkt:
- 297.96°C (rough estimate)
- Dichte
- 1.1860
- Brechungsindex
- 1.4459 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- L?slichkeit
- DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly)
- Aggregatzustand
- Crystalline Powder
- pka
- pK1: 4.57;pK2: 5.10 (25°C)
- Farbe
- White
- Optische Rotation
- [α]20/D 46°, c = 1 in ethanol
- Wasserl?slichkeit
- 0.8 g/100 mL
- Merck
- 14,1733
- BRN
- 2050204
- InChI
- 1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m1/s1
- InChIKey
- LSPHULWDVZXLIL-LDWIPMOCSA-N
- SMILES
- CC1(C)[C@H](CC[C@@]1(C)C(O)=O)C(O)=O
- CAS Datenbank
- 124-83-4(CAS DataBase Reference)
- NIST chemische Informationen
- D-camphoric acid(124-83-4)
- EPA chemische Informationen
- 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R,3S)- (124-83-4)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Kennzeichnung gef?hrlicher |
Xn |
|
|
| R-S?tze: |
22 |
|
|
| S-S?tze: |
24/25 |
|
|
| WGK Germany |
2 |
|
|
| TSCA |
TSCA listed |
|
|
| HS Code |
29172090 |
|
|
| Speicherklasse |
11 - Combustible Solids |
|
|
| Hazard Classifications |
Acute Tox. 4 Oral |
|
|
| Bildanzeige (GHS) |
|
| Alarmwort |
Warnung
|
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitssch?dlich bei Verschlucken. |
Akute Toxizit?t oral |
Kategorie 4 |
Warnung |
|
P264, P270, P301+P312, P330, P501 |
| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
|
P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
|
P264, P280, P305+P351+P338,P337+P313P |
|
| Sicherheit |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
|
d-Camphersure Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R22:Gesundheitssch?dlich beim Verschlucken.
S-S?tze Betriebsanweisung:
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
white to light yellow crystal powde
Verwenden
D-(+)-Camphoric acid is used primarily as a reagent in syntheses of crystalline structures. It is used in the preparation of polymeric transition metal dipyridylamine D-camphorate complexes.
Allgemeine Beschreibung
Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.
l?uterung methode
Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933
d-Camphersure Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
d-Camphersure Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 356)Lieferanten
124-83-4(d-Camphersure)Verwandte Suche:
- (1R,3S)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
- D-caMphor acid
- D(+)-CaMphoric acid, 99% 100GR
- (1RS,3SR)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid(caMphoric acid)
- (1R,3S)-(+)-Camphoric acid 99%
- (1R,3S)-(+)-Camphoric acid, >=99%
- 1,3-Cyclopentanedicarboxylicacid, 1,2,2-trimethyl-, (1R,3S)-
- (1R,3S)-(+)-Camphoric acid
D(+)-Camphoric acid
(1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
- 2,2-trimethyl-3-cyclopentanedicarboxylicaci(1theta-cis)-1
- Cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylicacid
- Dextro-camphoric acid
- (+)-CAMPHORIC ACID, NATURAL
- 1,2,2-Trimethyl-1,3-cyclopentanedicarbonsaeure
- (1R,3S)-(+)-Camphoric acid, 98+%
- (+)-Camphoric acid, (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
- cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid, (1R)
- 1,2,2-Trimethyl-1β,3β-cyclopentanedicarboxylic acid
- D(+)-Camphoric acid,99%
- D-(+)-Camphoric acid
- Levocarnitine EP Impurity B
- Levocarnitine Impurity 2（Levocarnitine EP Impurity B）
- (+)-Camphoric Acid >
- Levocarnitine Impurity B (D-(+)-Camphoric Acid)
- D-(+)-Camphoric acid USP/EP/BP
- (1R,3S)-1,2,2-trimethylcyclopentane-1,3-dicarboxylate
- 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-
- (1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid
- D-(+)-Camphoricaci
- (1R,3S)-(+)-Camphoric acid
- (1R)-cis-Camphoric acid
- (+)-CAMPHORIC ACID
- (1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid
- (1R,3S)-CAMPHORIC ACID
- (1R,3S)-(+)-CAMPHORIC ACID
- D-(+)-Camphoric
- 124-83-4
- Chiral Resolving Reagents
- Chiral Resolution Reagents
- Asymmetric Synthesis
- Optical Resolution
- Bicyclic Monoterpenes
- for Resolution of Bases
- Terpenes
- Bicyclic Monoterpenes
- Biochemistry
- for Resolution of Bases
- Optical Resolution
- Synthetic Organic Chemistry
- Terpenes
- Chiral Compound
- Pharmaceutical Intermediates
- FINE Chemical & INTERMEDIATES
- Miscellaneous Natural Products
- chiral
- bc0001
