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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Struktur
29964-62-3
CAS-Nr.
29964-62-3
Englisch Name:
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
Synonyma:
PdCl2(dppb);PDCI2(DPPB);Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II);[1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride;adium(II) DichL;[1,4-Bis(diphenyL;phosphino)butane]paL;Palladium(ii) chloride 1,4-b;[(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2;Bisdiphenylphosphinobutanepalladiumdichloride
CBNumber:
CB6185262
Summenformel:
C28H28P2.Cl2Pd
Molgewicht:
603.8
MOL-Datei:
29964-62-3.mol

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Eigenschaften

Schmelzpunkt:
285-305 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
L?slichkeit
Soluble in ethanol, benzene, and ethereal solvents.
Aggregatzustand
Powder
Farbe
light-yellow
InChI
1S/C28H28P2.2ClH.Pd/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28;;;/h1-12,15-22H,13-14,23-24H2;2*1H;/q;;;+2/p-2
InChIKey
JQXJBXVWVPVTOO-UHFFFAOYSA-L
SMILES
P(C1=CC=CC=C1)(CCCCP(C1=CC=CC=C1)C1C=CC=CC=1)C1=CC=CC=C1.[Pd](Cl)Cl
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn
R-S?tze: 36/37/38
S-S?tze: 24/25-36-27
WGK Germany  3
1-10
HS Code  28439000
Speicherklasse 13 - Non Combustible Solids
Bildanzeige (GHS) Exclamation Mark (GHS07)
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung
Sicherheit
P261 Einatmen von Staub vermeiden.
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P304+P340 BEI EINATMEN: Die Person an die frische Luft bringen und für ungehinderte Atmung sorgen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.
P405 Unter Verschluss aufbewahren.

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Chemische Eigenschaften,Einsatz,Produktion Methoden

S-S?tze Betriebsanweisung:

S24/25:Berührung mit den Augen und der Haut vermeiden.

Chemische Eigenschaften

yellow solid

Verwenden

Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II) is used for the catalysis of styrene carbonylation, coupling of alkyl Grignard reagents with organic halides, selective monoalkylation of organic polyhalides, and modification of the dihalovinyl moiety of synthetic pyrethroids.

synthetische

Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II) (1,4-Bis(diphenylphosphino)butane-palladium(II) chloride) can be prepared conveniently in situ by mixing the bidentate phosphine ligand and (PhCN)2PdCl2 in either benzene or chloroform.[1] The preparation of (dppb)PdCl2 is also possible through the reaction of PdCl2 with dppb in acetone, a process that slowly forms the catalyst as a white precipitate which can be isolated in 51% yield.[2] Preparation of the hydrate complex is possible via the reaction of Na2[PdCl4] with dppb in a mixture of CH2Cl2 and water.

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 254)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Honest Joy Holdings Limited
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ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
+86-13017695106 +86-13676922317
jiuyitime@fdachem.com China 16513 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21587 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 33024 60
career henan chemical co
+86-0371-86658258 +8613203830695
sales@coreychem.com China 29815 58
Nanjing Dolon Biotechnology Co.,Ltd.
18905173768
52513593@qq.com CHINA 2972 58
Accela ChemBio Inc.
+1-858-6993322
info@accelachem.com United States 21193 58
Alchem Pharmtech,Inc.
8485655694
sales@alchempharmtech.com United States 63687 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49979 58
Richest Group Ltd
18017061086
oled@richest-group.com CHINA 5600 58

29964-62-3()Verwandte Suche:


  • Palladium(ii) chloride 1,4-b
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride,98+%
  • Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II), Palladium(II) chloride 1,4-bis(diphenylphosphino)butane complex
  • Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%
  • 1,4-Butylenebis(diphenylphosphine)-palladium dichloride
  • Dichloro[1,4-bis(diphenylphosphino)butane]palladium (II) ,98%
  • 4-Bis(diphenylphosphino)butane-palladiuM(II) chloride
  • 1,4- double(twophenyl phosphinebutane)twopalladiuM chloride
  • [(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2
  • 1,4-bis (diphenylphosphino butane) palladiuM dichloride
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II)
  • dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
  • DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II)
  • 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II) CHLORIDE
  • 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE-PALLADIUM(II) CHLORIDE
  • [1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II) DICHLORIDE
  • PALLADIUM(II) CHLORIDE 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE COMPLEX
  • Bisdiphenylphosphinobutanepalladiumdichloride
  • PDCL2(DPPB)/ 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II)CHLORIDE
  • Palladium(II)chloride-1,4-bis(diphenylphosphine)butane
  • Dichloro 1,4-bis(diphenylphosphino)butane palladium (II) For use in coupling reactions
  • Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II),PdCl2(DPPB)
  • [1,4-Bis(diphenylphosphino) butane]dichloropalladium(II)
  • PdCl2(dppb) / dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
  • 4-diphenylphosphiniumylbutyl(diphenyl)phosphonium
  • [1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride >
  • [1,4-Bis(diphenylphosphino)butane]dichloropalladium(Ⅱ)
  • [1,4-bis(diphenylphosphino)butane] palladium(II)
  • [1,4-Bis(diphenyL
  • adium(II) DichL
  • phosphino)butane]paL
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride ISO 9001:2015 REACH
  • TIANFU-CHEM --1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
  • ichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
  • 1,4-bis(diphenylphosphinobutane)dichloropaladium
  • (SP-4-2)-[1,1′-(1,4-Butanediyl)bis[1,1-diphenylphosphine-κP]]dichloropalladium
  • [1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride
  • Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II)
  • PDCI2(DPPB)
  • PdCl2(dppb)
  • 29964-62-3
  • C28H28Cl2P2Pd
  • C28H28Cl2P2Pd2
  • C28H28P2Cl2Pd
  • Homogeneous Pd Catalysts
  • Catalysis and Inorganic Chemistry
  • Homogeneous Catalysts
  • Pd (Palladium) Compounds
  • Metal Complexes
  • Classes of Metal Compounds
  • Catalysts for Organic Synthesis
  • Transition Metal Compounds
  • Pd (Palladium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
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