4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE
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- CAS-Nr.
- 19312-06-2
- Englisch Name:
- 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE
- Synonyma:
- 4,4-dimethyl-2-phenyl-2-azoleline;4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE;4,4-Dimethyl-2-phenyl-2-oxazoline 96%;Oxazole, 4,5-dihydro-4,4-dimethyl-2-phenyl-;4,4-Dimethyl-2-phenyl-4,5-dihydro-1,3-oxazole;4,4-Dimethyl-2-phenyl-2-oxazoline
- CBNumber:
- CB6376123
- Summenformel:
- C11H13NO
- Molgewicht:
- 175.23
- MOL-Datei:
- 19312-06-2.mol
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4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Eigenschaften
- Schmelzpunkt:
- 20-24 °C(lit.)
- Siedepunkt:
- 124 °C20 mm Hg(lit.)
- Dichte
- 1.025 g/mL at 25 °C(lit.)
- Brechungsindex
- n20/D 1.5322(lit.)
- Flammpunkt:
- 217 °F
- storage temp.
- 2-8°C, stored under nitrogen
- pka
- 4.82±0.70(Predicted)
- Aussehen
- Colorless to off-white <20°C Solid,>24°C Liquid
- BRN
- 132225
- InChI
- 1S/C11H13NO/c1-11(2)8-13-10(12-11)9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
- InChIKey
- UGNSMKDDFAUGFT-UHFFFAOYSA-N
- SMILES
- CC1(C)COC(=N1)c2ccccc2
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Verwenden
4,4-Dimethyl-2-phenyl-2-oxazoline may be used in the synthesis of an ester-ammonium salt via rupture of oxazoline ring.
Synthesis Reference(s)
Journal of the American Chemical Society, 82, p. 2032, 1960
DOI: 10.1021/ja01493a045Tetrahedron Letters, 27, p. 5269, 1986
DOI: 10.1016/S0040-4039(00)85187-4
Allgemeine Beschreibung
4,4-Dimethyl-2-phenyl-2-oxazoline is an 2-aryl-2-oxazoline and has been tested as as ligand for the Suzuki coupling reaction of aryl bromides and arylboronic acids. 4,4-Dimethyl-2-phenyl-2-oxazoline forms mildly hygroscopic complexes, of general formulae [ZnX
2(ox)
2] (ox =4,4-Dimethyl-2-phenyl-2-oxazoline), with ether solutions of [ZnX
2] (X = Cl, Br, I).Except ZnI
2, which does not form an isolable complex due to steric reasons.
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 46)Lieferanten
- 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE
- 4,4-Dimethyl-2-phenyl-2-oxazoline 96%
- 4,4-Dimethyl-2-phenyl-4,5-dihydro-1,3-oxazole
- Oxazole, 4,5-dihydro-4,4-dimethyl-2-phenyl-
- 4,4-Dimethyl-2-phenyl-2-oxazoline
- 4,4-dimethyl-2-phenyl-2-azoleline
- 19312-06-2
- Heterocyclic Building Blocks
- Oxazolines/Oxazolidines
- Building Blocks
- Building Blocks
- Heterocyclic Building Blocks
- Oxazolines/Oxazolidines
